氟化物强化石煤提钒机理研究-矿物加工工程专业论文.docx

万方数据 万方数据 Abstract At present, there are generally low leaching efficiency of vanadium and high acid consumption for vanadium extraction from stone coal. However, fluoride can effciently enhance vanadium leaching process. This thesis focused on the theory of fluoride in enhancing vanadium leaching from stone coal and the effects of fluoride on solvent extraction. Through comparing the changes of vanadium leaching and solvent extraction with fluoride introduced for vanadium extraction from stone coal, the mechanism of fluoride in enhancing vanadium leaching can be concluded: F reacted with Al and Si to generate [SiF6]2- and [AlF5]2- during vanadium leaching process, which facilitated releasing vanadium into leachate and declined the influence of chemical reaction on vanadium leaching. This made the previous vanadium leaching controlled by chemical reaction transformed to that controlled by internal diffusion. These changes accelerated vanadium leaching and increased the efficiency and rate of vanadium leaching. Through comparison of vanadium leaching behavior of three typical kinds of stone coal during direct acid leaching process and blank roasting acid leaching process, it was found that occurance of vanadium and iron and content of acid-consuming minerals like calcite in raw stone coal and blank roasting have great effects on vanadium leaching efficiency of vanadium. On the one hand, blank roasting benefited the vanadium leaching because of transforming vanadium (bound to organics) into vanadium (bound to free oxide) and breaking vanadium-bearing silicoaluminate minerals down. On the other hand, it also made Pyrite transformed into acid-consuming Hematite, which increased the consumption of hydrofluoric acid. It was the generation of Hematite covering the benefits from blank roasting that decreased the leaching efficiency of vanadium. It was reasonable for this stone coal where vanadium and iron mainly existed in forms of silicoaluminate and Pyrite respectivel