微波水热时间对ZnWO4纳米晶形貌及光学性能的.pdf

40 9 pH MnWO4 1331 40 9 Vol. 40 No. 9 2 0 1 2 9 JOURNAL OF THE CHINESE CERAMIC SOCIETY September2012 ZnWO4 1 1 1 2 1 (1. 710021 2. 528211) Na WO 2H O Zn(COOCH ) 2H O X 2 4 · 2 3 2 · 2 – 180 10min ZnWO4 ZnWO4 3.773.89 eV TB32 A 0454–5648(2012)09–1331–04 2012–08–21 15:42:49 /kcms/detail/11.2310.TQ1542.201209.1331_015.html Influence of Reaction Time on Morphology and Optical Property of ZnWO4 Nanocrystallites Prepared by Microwave Hydrothermal Process ZHANG Xiaowei1 1 1 2 1 CAO liyun HUANG Jianfeng LIU Yijun LI Jia (Key Laboratory of Auxiliary Chemistry Technology for Chemical Industry, Ministry of Education, Shaanxi University of Science Technology, Xi’an 710021, China; 2. Guangdong Monalisa Ceramics Co., Ltd. Foshan 528211, Guangdong, China) Abstract: The wolframite zinc tungstate nanocrystallites were prepared by a microwave hydrothermal method in the absence of template with Na WO ·2H O and Zn(COOCH ) ·2H O as start materials. The phase, morphology and optical properties of the as-prepared 2 4 2 3 2 2 samples were characterized by X-ray diffraction, transmission electron microscopy and UV–Vis absorption spectra, respectively. The results indicated that the wolframite ZnWO nanocrystallites can be obtained by the microwave hydrothermal method at 180 for 4 only 10 minutes. The morphol