临位导向的C-H活化偶联反应.PDFVIP

Electronic Supplementary Material (ESI) for Organic Chemistry Frontiers. This journal is © the Partner Organisations 2014 Electronic Supplementary Information for Acenaphthoimidazolium Chloride Enabled Nickel Catalyzed Amination of Bulky Aryl Tosylates Jian Jiang, Haibo Zhu, Yajing Shen and Tao Tu * Department of Chemistry, Fudan University 220 Handan Road, 200433, Shanghai, China Email: taotu@fudan.edu.cn Table of contents: 1 General ······················································································ S2 2 Experimental sections ··································································· S2 3 Synthesis of acenaphthoimidazolium chloride········································ S3 3.1 General procedure for Ni-NHC catalyzed amination····························· S3 3.2 Optimization of reaction conditions ··············································· S4 4 Data for the amination products················································ S4 5 1H NMR, 13C NMR and MS spectra for important compounds ···················· S14 6 References··················································································· S41 S1 1. General All commercial reagents were used directly without further purification, unless otherwise stated. Dry dimethylsulfoxide (DMSO) was purchased from J K chemical, stored over 4 Å molecular sieves and handled under N . Anhydrous methanol (MeOH) was distilled from 2 anhydrous calcium chloride, Dioxan