TiSiW12O40TiO2催化合成阻燃剂.PDFVIP

10 1 () Vol. 10 No. 1 2010 3 JOURNAL OF NANJING NORMAL UNIVERSITY( ENG INEER ING ANDTECHNOLOGY ED IT ION) M ar, 2010 T iSiW O /T iO 催化合成阻燃剂 12 40 2 磷酸三( 1-氯-2-丙基)酯 罗 炜, 张士磊, 周 浩, 王 丹, 杨锦飞 ( , 210097) [] (POC l ), T iSWi O /T iO ( 1--2-) 3 12 40 2 (TCPP), . : n (POCl ) Bn () = 1B313, 65e ~ 75e , 110%, 5 h, 3 941 8% . [] , ( 1--2-)(TCPP), [] T 460. 31 [] A [] 1672-1292( 2010) 01-0059-04 Catalytic Synthesis of Tris(1-Chloro-2-Propyl) Phosphate Flame Retardantby SolidAcid Luo W e,i Zhang Sh iel ,i Z hou Hao, W ang D an, Y ang J infe i ( School of Chem istry and Environment Science, NanjingNormalUniversity, Nanjing 210097, China) Abstract: Tris( 1-chloro-2-propyl) phosphate(TCPP) was synthesized with phosphorus oxychloride and propylene epox- ide as raw materials, using T iSWi O /T iO made by ourselves as catalyst for the reaction. The influences of reaction 12 40 2 temperature, the ratio of reactants, the amount of catalyst and reaction tmi ewere studied. Itwas shown that the proper reaction conditions were: the molar ratio of propylene epoxide to phosphorus oxychloridewas 1B3. 3, reaction tempera- turewas 65e ) 75e , themass of catalystwas 110% ofphosphorus oxychloride, dropwise tmi e ofpropylene oxidewas 5 h. The yield ofTCPP was about 941 8%. K ey ords: flame retardant, tris( 1-chloro-2-propyl) phosphate(TCPP), synthesis ( 1--2-)(2-)( B-), TCPP. , ,. TCPP()