Pb3O4层引入对钛基PbO2电极强化寿命影响.PDFVIP

41 3 Vol.41, No.3 2012 3 RARE METAL MATERIALS AND ENGINEERING March 2012 Pb O PbO 3 4 2 ( 710049) SnO -Sb Pb O 2 3 4 Pb3O4 100.5 h 970 h XRFXRD SEM Pb3O4 PbO2 PbO2 TG146.1+2 A 1002-185X(2012)03-0462-05 Ti/SnO -Sb O -CF/PbO 2 2 4 x Ti/SnO2 -Sb/PbO2 SnO -Sb PbO 2 2 Pb O Pb O 3 4 3 4 [1,2] Pb Sn 1 PbO2 Pb Sn PbO Pb O 2 3 4 Sn PbO2 PbO2 Pb3O4 Sn Sn PbO2 Sn-Sb SnO2 [3] TiO2 SnO2 [4] 2 cm×2 cm TA2 23 μm [5]Ti 1:1 PbO2 MnO2 10%NaOH 1 h 2 PbO2 PbO2 10% 2 h PbO2 PbO2 Song[6]PbO Ce(NO ) Sn:Sb=10:1 2 3 2 PbO2 - CeO2 PbO2 PbO2