化学镀在钯复合膜制备及石墨电极修饰中的应用研究-工业催化专业论文.docxVIP

battery. However, Cu modified electrode is not suitable for this system. The metals were deposited with an electroless plating method. An ionic liquid (Tetraethylammonium hexafluorophosphate amines, TEAPF6) was used as the supporting electrolyte. Acetylacetone vanadium was used as the active substance, and acetonitrile as the solvent. Cyclic voltammetry were tested under anhydrous anaerobic conditions. The electrode kinetics study shows that the V(Ⅱ)/V(Ⅲ) and V(Ⅲ)/V(Ⅳ) redox reaction are subjected to irreversible reactions, the diffusion coefficient of acetylacetone vanadium is about 1.21×10-6 cm2/s at room temperature, and the electrode reactions are diffusion controlled. The graphite electrodes are also treated with heating at 200-400 oC to further improve the electrochemical activity. When treated at 400 oC, the electrochemical activity improved to a certain extent. However, when the temperature is higher than 600 oC, the electrochemical activity decreased due to the excessive oxidation of the reactive functional groups. KEY WORDS：Electroless plating, ultrasonic, palladium composite membrane, hydrogen permeation, graphite electrodes modification, vanadium redox flow battery  目 录  HYPERLINK \l _bookmark0 第一章 绪论 1  HYPERLINK \l _bookmark1 1.1 化学镀研究进展 1  HYPERLINK \l _bookmark2 1.1.1 引言 1  HYPERLINK \l _bookmark3 1.1.2 改进化学镀 1  HYPERLINK \l _bookmark4 1.1.3 超声波作用机理 2  HYPERLINK \l _bookmark5 1.1.4 化学镀影响因素 5  HYPERLINK \l _bookmark6 1.2 钯复合膜的研究进展 6  HYPERLINK \l _bookmark7 1.2.1 文献综述 6  HYPERLINK \l _bookmark8 1.2.2 钯膜透氢机理 8  HYPERLINK \l _bookmark9 1.2.3 金属膜的制备方法及研究现状 10  HYPERLINK \l _bookmark10 1.3 全钒液流电池研究进展 11  HYPERLINK \l _bookmark11 1.3.1 引言 11  HYPERLINK \l _bookmark12 1.3.2 液流电池原理 11  HYPERLINK \l _bookmark13 1.3.3 电极修饰 12  HYPERLINK \l _bookmark14 1.4 论文研究内容和意义 14  HYPERLINK \l _bookmark15 第二章 改进化学镀法制备钯复合膜及其性能研究 15  HYPERLINK \l _bookmark16 2.1 前言 15  HYPERLINK \l _bookmark17 2.1.1 复合膜