壳聚糖季铵盐絮凝剂处理丁苯橡胶废水的研究.PDF

中国环境科学 2012,32(2) ：232~237 China Environmental Science 壳聚糖季铵盐絮凝剂处理丁苯橡胶废水的研究 * 常 青 ,韦 俊 (兰州交通大学环境与市政工程学院,甘肃 兰州 730070) 摘要：以壳聚糖(CTS)为母体,3-氯-2-羟丙基三甲基氯化铵(CTA)为改性剂,合成了壳聚糖季铵盐阳离子型高分子絮凝剂 2-羟丙基三甲基氯 化铵壳聚糖(HTCC), 以其对高岭土悬浊液的浊度去除率为指标优化合成条件, 以 HTCC 分别与 PAC 及 PAM 复配,絮凝处理丁苯橡胶废水. 结果表明,最佳合成条件为:质量比 MCTS : MCTA : MNaOH =1:2:1.2 、反应温度 60℃、反应时间 3h,在此条件下合成的 HTCC 对高岭土悬浊液的 浊度去除率达 96.46%;HTCC+PAC 复配在 pH6.0~8.0 对丁苯橡胶废水的絮凝效果较好,出水余浊2NTU,色度去除率达 92.98%,COD 去除率 达 32.0%;HTCC+PAM 复配在 pH5.0~8.9 对丁苯橡胶废水的絮凝效果最好,余浊3NTU,COD 去除率 46.0 %,且投药量小, pH 适宜范围宽,优 势比较明显.以 HTCC 与 PAC 、PAM 分别复配处理丁苯橡胶废水可减轻后续生化处理的负荷,降低 PAC 、PAM 的投加量,从而减小出水中 残余铝和残余丙烯酰胺单体的含量. 关键词：季铵盐；壳聚糖；絮凝；丁苯橡胶；废水处理 中图分类号：X703.5 文献标识码：A 文章编号：1000-6923(2012)02-0232-06 Preparation of chitosan quaternary ammonium and flocculation of styrene-butadiene rubber wastewater. CHANG * Qing , WEI Jun (School of Environmental and Municipal Engineering,Lanzhou Jiaotong University, Lanzhou 730070, China). China Environmental Science, 2012,32(2)：232~237 Abstract ：Cationic flocculant 2-hydroxypropyltrimethyl-ammonium chloride chitosan (HTCC) was prepared by the reaction of chitosan (CTS) with 2-hydroxypropyltrimethyl-ammonium chloride (CTA). The optimum synthesis conditions of HTCC was determined according to its turbidity removal efficiency for kaolin suspension as follows: mass ratio MCTS: MCTA : MNaOH =1:2:1.2, reaction temperature was 60 ℃ and reaction time was 3h. The flocculation experiment showed the turbidity removal efficiency of HTCC was higher, and the applicable pH range of HTCC was broader compared to CTS. The styrene-butadiene rubber wastewater was treated by the composite flocculant HTCC+PAC. The residual turbidity reached under 2 NTU, the removal rates of COD and chromaticity reached to 32.0% and 92.98% res