氧化钇分离提纯技术的进展-有色金属冶炼部分.DOC

doi： doi：10.3969/j.issn.1007-7545.2018.11.013 韩旗英1，周勇1，张魁芳2，刘志强2，凌诚1，韩新福1，钟德强1 （1.广东富远稀土新材料股份有限公司，广东 平远 514600；2.广东省稀有金属研究所，广州 510650） 摘要：介绍了钐铕钆富集物为原料，用P507全萃取分离方法分离生产激光级氧化铕的生产方法和工艺流程，并与传统还原—萃取分离法进行比较，明确了全萃取分离方法的优越性，指明了高纯氧化铕生产的发展方向。研究表明，全萃取分离方法可取消锌粉还原工序，克服锌粉带来的渣量大、重金属废液污染严重、氢气安全隐患大等弊端，同时具有可连续生产，操作控制方便、成本低等优点，每吨氧化铕生产成本可降低近5万元。 关键词：氧化铕；全萃取分离法；激光级 中图分类号：TF845；TF803.23 文献标志码：A 文章编号：1007-7545（2018）11-0000-00 Production of Laser Grade Europium Oxide by Direct Extraction Separation HAN Qi-ying1, ZHOU Yong1, ZHANG Kuí-fang2, LIU Zhi-qiang2, LING Cheng1, HAN Xin-fu1, ZHONG De-qiang1 (1. Guangdong Fuyuan Rare Earth New Material Co. Ltd., Pingyuan 514600, Guangdong, China; 2. Guangdong Province Research Institute of Rare Metals, Guangzhou 510650, China) Abstract：Production method and process of laser grade europium oxide by P507 complete extraction separation method with samarium, europium, gadolinium enrichment as raw materials were described and compared with traditional zinc powder reduction-extraction separation method. The advantages of direct extraction separation and development direction of high purity europium oxide production were put forward. The results show that direct extraction separation method can eliminate zinc powder reduction process, which has the disadvantages of large slag quantity, serious heavy metal waste liquid pollution, and large potential safety hazards of hydrogen. At the same time, it has many advantages including continuous production, convenient operation control and low production cost. Production cost of per ton of europium oxide can be reduced by nearly 50 000 Yuan RMB by direct extraction separation method. Key words：europium oxide; direct extraction separation method; laser grade 稀土铕以其独特的化学性质被广泛应用于稀土发光材料、荧光材料以及原子反应堆的控制材料、屏蔽材料和结构材料等高端技术领域。随着面向高、精、尖高端技术的不断发展，氧化铕需求量明显提高。与此同时，对氧化铕纯度也提出了更高的要求。为此，优化和设计高纯氧化铕（Eu2O3/TREO＞99.99%）分离提纯工艺具有重要的战略意义，也是氧化铕生产的必然趋势。 1 试验部分 1.1 主要原辅材料和设备 钐铕钆富集物：试验所用的钐铕钆富集物为本公司用我国南方离子型稀土矿经过萃取分组得到的钐铕钆富集物的氯化物溶液，料液组分（%）：Nd2O