过渡金属化合物为高效催化剂有氧氧化生物质衍生5-羟甲基糠醛生成2,5-二甲酰基呋喃的研究探究新.pdfVIP

Studies in Synthetic Chemistry 合成化学研究, 2014, 2, 41-49 Published Online June 2014 in Hans. /journal/ssc /10.12677/ssc.2014.22005 Transition Metal Compounds as Efficient Catalysts in Aerobic Oxidation of Biomass-Derived 5-Hydroxymethylfurfural to 2,5-Diformylfuran Shengqiang Zhang, Weifeng Li, Lu Lin* School of Energy Research, College of Energy, Xiamen University, Xiamen * Email: joseph201x@ , lulin@ th th st Received: Apr. 30 , 2014; revised: May 26 , 2014; accepted: Jun. 1 , 2014 Copyright © 2014 by authors and Hans Publishers Inc. This work is licensed under the Creative Commons Attribution International License (CC BY). /licenses/by/4.0/ Abstract 2,5-diformylfuran (DFF) is one of the important platform molecules derived from 5-hydroxymethyl- furfural (HMF) or other bio-based carbohydrates, which has lots of potential applications in many fields of organic synthesis industry. This compound has become a research focus in recent years due to its relatively high price and immature synthesis technology. To realize the industrial pro- duction of DFF in the future, many methods have been attempted to achieve this product efficient- ly. In this research, some transition metal compounds and lanthanides, including Nb O , V O , 2 5 2 5 C F O S Yb·xH O, Na VO , KVO and MnO , were adopted as plausible high-efficiency catalysts in 3 9 9 3 2 3 4 3 2 aerobic oxidation of biomass-derived model molecule 5-Hydroxymethylfurfural (HMF) with the purpose