《纳米锡基氧化物电极材料—水热合成法及电化学性能》-毕业设计论文（学术).docVIP

大连理工大学本科毕业设计（论文） 新型超级电容器电极材料—锡化合物/碳复合体 Novel electrode material of supercapacitor—tin compound/C composites 学 院（系）： 化工学院 专 业： 电化学工程 学 生 姓 名： 学 号： 指 导 教 师： 评 阅 教 师： 完 成 日 期： 大连理工大学 Dalian University of Technology 摘 要 超级电容器是一种新兴的储能元件，因其具有高比能量、良好的可逆性和长循环寿命，近年来国内外对超级电容器的应用研究非常活跃。人们普遍认为，沉积在碳表面上的过渡金属氧化物，如钌，铱，钨，钼，锰，镍，锡等，能被广泛的利用来增加电容器的电容值。本论文主要讨论了利用金属锡增加电容值。 本文以结晶四氯化锡和聚乙烯醇为原料，通过改变无水碳酸钾的量来改变比表面积，采用高温碳化的方法合成出新型超级电容器材料—锡化合物/碳复合体。通过循环伏安、恒流充放电等测试手段对样品的电化学性能进行测试。 以该材料作为工作电极，利用循环伏安法与恒流充放电法在三电极体系下考察了不同无水碳酸钾含量下的电化学性质，发现电容器的比电容量基本上是随着无水碳酸钾含量的增加而增加，说明碳酸钾添加显着增加主要原因Novel electrode material of supercapacitor—tin compound/C composites Abstract Supercapacitor is a new energy storage component. Nowadays supercapacitor has become a researching hotspot for its high specific capacitance, excellent reversibility and long cyclic performance. Deposition of transition metal oxides, such as Ru, Ir, W, Mo, Mn, Ni, Co etc., on the carbon surface is widely utilized in order to increase the capacitance. This dissertation concentrates on studying of tin compound/C composite with the goal of increasing capacitance. In this dissertation, the novel electrode material of supercapacitor—tin compound/C composite is successfully synthesized by high temperature carbonization of SnCl4 and hydrolyzed poly(vinyl alcohol). A certain amount of anhydrous potassium carbonate is used to adjust the specific surface area. Electrochemical properties of the resultant are investigated in a three electrode system by cyclic voltammetric measurements(CV), constant charge/discharge measurement and electrochemical impedance spectroscopy (EIS). It is found that the specific capacity of the tin compound/C composite increase with increasing the amount of anhydrous potassium carbonate added. This indicates that the addition of anhydrous potassium carbonate mainly causes a significant increas