高功率型磷酸铁锂动力电池的研制-物理化学专业论文.docxVIP

II II Abstract Currently, the new industrialization, which take the “low-carbon and circular economy” as the subject, is promoting the new energy vehicles industry development. Hybrid electric vehicle(HEV) is the fastest developing new energy vehicle, and high-power lithium-ion power battery with the high-performance can well satisfy the requirements of HEV. Cathode material is one of the most critical materials for the high-power lithium-ion power battery. Among them, LiFePO4 is the preferred cathode material for high-power lithium-ion power battery due to its long cycle life, high thermal stability, green environmental protection, abundant resources and low cost. However, the low electron conductivity and slow Li-ion diffusion rate of the material lead to poor rate capability, which greatly limit its application on high-power lithium-ion power battery. In this paper, LiFePO4/C composite was prepared by two-step high temperature solid state reaction. The effects of calcination temperature, carbon source and addition amount of carbon on the structure, morphology and properties of the material were investigated by XRD, SEM and electrochemical testing. The results showed that the LiFePO4/C composite synthesized at 700℃ with 6.4% mass percentage of carbon which using glucose as carbon source had the ordered olivine-type LiFePO4 structure and displayed best electrochemical performance. The constant charge-discharge tests showed that the special discharge of 126.2mAh/g, 111.8mAh/g and 88.2mAh/g were obtained at 1C, 2C and 4C, respectively. Doping is an effective way to improve the performance of LiFePO4/C composite. Zr4+ doped-LiZryFe1-2yPO4/C (y = 0, 0.01, 0.03, 0.05) and Y3+ doped-LiYyFe1-1.5yPO4- /C (y = 0, y = 0.01, y = 0.02, y = 0.03) were obtained by two-step high temperature solid state reaction under the optimum conditions. The effects of the contents of Zr4+ doped and Y3+ doped on the properties of LiFePO4/C composite were studied by XRD, SEM, constant charge-di