AuPt掺杂TiO2空心微球的制备及电性能研究.docx

优秀毕业论文 精品参考文献资料 Au／ Au／Pt掺杂Ti02空心微球的制各及光电性能研究 Preparation and Photoelectric Performance of Au／Pt doped Ti02 Hollow Mi crospheres Abstract Ti02，a multi—functional semiconductor material，is applied in optoelectronic fields since it is non-toxic，stable and wildly abundant．But the limitations such as wide band gap，low surface area and surface defects affect its performances．Many strategies have been proposed for optimizing photoelectric performance of Ti02，with fine control of its morphology being one of the most effective．Hollow sphere materials possess good light scattering，larger surface area and tunable morphology，showing good performance in applications．Besides， numerous investigations reported that the addition of noble metals including gold and platinum iS also an effective way to enhance the photoelectric performance．Due to high Schottky barrier between metal and Ti02，it not only eliminates the recombination of electrons and holes by increasing the charge separation，but also extends the wavelength range response by photosensitization．In this thesis，Au／Pt doped Ti02 hollow spheres which integrate superiorities of hollow spheres structures and noble metal were prepared and the related photoelectric properties of the materials were investigated． A novel Ti02 hollow microsphere was synthesized by solvethermal method．following by depositing controllable nano—Au through an effective and facile in situ reduction approach to obtain Ti02／Au composites．The effect of nano．Au on Ti02S photoelectric performance was evaluated by the degradation of methylene blue(MB)under UV or visible light irradiation．It was found that the Au doped Ti02 hollow spheres show excel lent photocatalytic properties and extend the light absorption spectrum into the visible region．Ti02／Au composites exhibit the fastest degradation rate of MB when the weight percent of the deposited Au nanoparticles is 2．8 wt％．Furthermore，the Ti02／Au(Au，2．8 wt％)catalyst exhibits MB removals of 99．77％under UV irradi