BN负载贵金属催化桂醛选择性加氢反应研究-化学工程与技术专业毕业论文.docxVIP

广东工业大学硕士学位论文 Abstract Cinnamaldehyde(CAL)is one of the typical representative a，13-unsaturated aldehydes， which Call be hydrogenated to cinnamyl alcohol(COL)，a widely used chemical in perfume and pharmaceutical industry,or hydrocinnamaldehyde(HEAL)，an important intermediate of anti-HIV drug．Further hydrogenation of COL and HCAL leads to the formation of 3-phenyl． 1-propanol(PPL)．Although the hydrogenation of C=C is thermodynamically favorable than that of C=0 group，the mixture of various products is generally obtmned in CAL hydrogenation and the mechanism of selecvitity is not clear SO far．Th