AlTi复合脱氧镁钙处理钢中夹杂物特征对腐蚀为的影响.docx

优秀毕业论文 精品参考文献资料 个／mm2)没有关系。 (4)点蚀试验结果表明：与钛脱氧钢相比，铝脱氧钢的自然腐蚀速度更快； 与铝脱氧钢相比，钛脱氧钢的耐点蚀性能更强，与钙处理方式相比，镁处理钢 的耐点蚀性能更强；夹杂物是钢中点蚀的诱发源，腐蚀首先在夹杂物与钢基体 界面处形成。并且，夹杂物尺寸越大，其与钢基体界面上腐蚀的钢越多，腐蚀 越严重。 关键词：X80管线钢；氢致裂纹；点蚀；夹杂物；脱氧方式 万方数据  Abstract Along with the development of deep sea oil field resources，the existence of chlorine ion／hydrogen sulfide gas in the energy causes the corrosion of the pipeline steel which is induced by inclusions．The inclusions have been shown to be seriously harmful to the safety and stability of the pipeline．In order to investigate the effect of the Ti-deoxidization and Mg／Ca treatment on the Characteristics of inclusions，and on the corrosion behavior(HIC and pitting corrosion)compared to that in the A1-deoxidization and Ca／Mg treatment，experiments were conducted in a 25 kg medium frequency vacuum induction fumace．The steels were rolled into sheets by thermo-mechanical control processing(TMCP)．The morphology，composition， deformation and distribution of inclusions in the as．casted and rolled steel were characterized．The HIC susceptibility was evaluated by NACE Standard TM 0284-20 1 1 method．The pitting corrosion was evaluated by the experiment of natural corrosion and electrochemical polarization．The results are as follows． (1)Compared to the A1一deoxidized steels，the number density of the inclusions with sphere or ellipsoid morphology in the Ti-deoxidized steels was relatively large， the size Was small and the ratio of inclusions in the interval of small deformation aspect ratio(1—3)were large，respectively． (2)Compared to the as-casted steels，the composition of inclusion did not obviously changed，but the morphology，distribution，number and deformation interval greatly changed．The morphology of inclusions in as-casted steels were sphere，while their morphology turned into ellipsoid or elongated in the rolled steels．The average size of inclusions and the number of large inclusion increased，the number density of the inclusions decreased owing to the deformation of