HR3C钢中σ相析出动力学究-材料学专业毕业论文.docxVIP

HR3C钢中。相析出动力学研究Study HR3C钢中。相析出动力学研究 Study on Precipitation Kinetics of o Phase in HR3 C Austenitic Stainless Steel Abstract HR3 C steel，as a new type of austenitic heat resistant steel，is widely used in supercritical unit as superheater and reheater tube for its high creep strength，especially excellemt high temperature oxidation resistance．Since the life of ultra-supercritical power plant equipment is 30 to 40 years，the component steels should have good stability．But when aging for long time under high temperature and high pressure service condition，microstructure and phase structure of component steel would degraded，resulting in the loss of operation safety and reliability，even early failure．For this reason，it is of great importance to study microstructure stability，mechanical properties changes and reliability during the process of serving of HR3C steel． At present．there have been a lot of researchs on precipitation of NbCrN，M23C6 and Nb(C，N)phases during serving and their influences on the properties of HR3C steel，only a few reseachers have reported 6 phase precipitation issue．The precipitation of o phase in HR3C steel Was regarded to be restrained due to the composition design，but recent studies have revealed its problem of turning brittle after service．Our previous work focused on Sumitomo HR3C steel aged at 700℃～800℃and found the precipitation of o phase．It iS generally believed that precipitation of 6 phase would significantly reduce mechanical properties and creep performace of materials，SO more investigations needed to be conducted on o phase precipitation behavior and its effect on properties in HR3C steel． This work confirmed the precipitation of o phase in HR3 C steel aged at high temperature by metallographic microscope，X-ray diffraction analyzer，scanning electron microscope and SO on，and analyzed the kenitics behavior of o phase precipitation by chromogenic corrosion semi—quantitative method combined with Avrami equation．Besides，properties changes of