高级氧化技术降解苯酚水样的研究-环境工程专业论文.docxVIP

山东建筑大学硕士学位论文Study 山东建筑大学硕士学位论文 Study on degradation of phenol in water by advanced oxidation technology LiU Chenchen (Environmental E晤neering Directed by Wu Junsen) ABSTRACT With the rapid growth of population and economy，the technology of micro—polluted water treatment has attracted more and more attention,the traditional micro—pdluted water treatment agent in the treatment process easy to form Secondary pollution,it Can no longer satisfy people’S demands．This paper selects phenol which is a typifacation of phenolic compounds as the research object．The feasibility and influencing factors are studied in the degradation of phenolic compounds by ultrasonic cavitation、H202、Fenton reagent and the combinition of ultrasonic and Fenton technology．The subject intends to search a kind of disposal method which makes some bases for the treatment of industrial wastewater The result shows that the degradation rate of phenol by ultrasonic cavitation alone is not hi#．With two hours treatment，the phenol removal rate of the concentration of l Omg／L of phenol solutionjust reached 1 0．9％ Under acidic conditions，Hydrogen peroxide has strong oxidation,when the pH value was 3，the phenol degradation rate was the highest．In practical engineering，the adjustment of the pH process is complex and may form secondary pollution．It is difficult to reach the standard of drinking water if we do not adjust the pH value of the solution Fentons reagent is more efficient than using hydrogen peroxide alone and using ultrasonic oxidation alone，it carl achieve a relatively high degradation rate in a relatively short time．According tO the experimental study of phenol solution of 1 0megL，the best ratio of ferrous sulfate and hydrogen peroxide in Fenton reagent was 1：61．In the treatment of lmg／L phenol solution under the conditions of this ratio，phenol was completely degraded in half an hour． The syne哂stic effect of the combined action of ultrasound and Fenton reagent on the treatment of phenol was obvious