高耐热及导热多孔硅橡胶合金的制备与表征-材料学专业论文.docxVIP

Subject :High heat resistance thermal conductivity of porous silicone rubber alloy Preparation and Characterization Speciality :Material Science Name :Song Chang qing （Signature） Instructor :Shao Shui yuan （Signature） ABSTRACT Porous silicone rubber, also known as foam silicone rubber, sponge silicone rubber, is a new kind of material with the silicone rubber and foam material properties. Not only has a low density, good absorption of mechanical vibration or shock, insulation and sealing, and has excellent heat resistance. This thesis is focused on preparing foam silicone rubber materials and increasing its heat resistance by a variety of impact factors. Combined with a foaming additives to the blowing agent H 2 and added 30% of the silica, using the circular mold and setting capacity given pressure molded foam process to prepare porous silicon rubber material, obtained silicone rubber vulcanization and foaming a good match, the best overall performance, density 588Kg/m3, foaming magnification of 1.9 times ,the bubble hole was closed and oval pore structure, distributed evenly, the hardness of foam silicone rubber is 24.3 degrees, rebound rate of the ball drop is 31.4%, the tensile strength is 0.64MPa, the elongation at break is 249.8%. On the basis of the above materials prepared, adding crosslinker, homemade alloy components hydroxy-terminated poly dimethyl siloxane such as modified from the structure, as well as different types of thermally conductive fillers, such as heat-resistant filler to get four types of heat-resistant foam silicone rubber, improved methods of foam silicone rubber foam structure were studied by TGA, hardness, rate of drop-ball rebound, infrared spectroscopy, microscopy analysis, hot air aging, etc. The results showed that: the alloy components on the foam of the foam silicone rubber has an adverse effects on the thermal conductivity of the fillers and heat-resistant filler joined foam silicone rubber foaming and foaming process; allo