Ni催化作用下低碳MgOC火材料的显微结构特征及其性能研究.docxVIP

的试样在经1200。C埋炭热处理后原位生成碳纳米管(CNT)和MgAl204晶须；经 1400。C热处理后，试样中碳纳米管直径增大，长度变短，MgAl204晶须生成量增 多；其中Ni(N03)2·6H20添加量为0．6wt．％的试样综合性能较优。 关键词：低碳MgO—C耐火材料；MgAl204；晶须；催化剂；显微结构 万方数据  Abstract In this paper,low—carbon MgO—C refractories were studied．The phase composition and microstructure evolution of specimens were analyzed by techniques of X-ray diffraction，scanning electron microscope，transmission electron microscope and energy dispersive spectrometer．The cold modulus of rupture，cold crushing strength， force—displacement curves，flexural modulus，and hot modulus of rupture and thermal shock resistance of specimens were tested．The effects of antioxidants(Mg-AI alloy and metallic Si powder)and the content of catalyst(Ni(N03h’6H20)on mechanical properties and microstructure characteristics of low··carbon MgO·-C refractory samples were studied．The growth mechanism model of in-situ MgO whisker formation under the action of catalyst was established． The effects of Ni(N03h。6H20 catalyst and antioxidants of Mg—A1 alloy and metallic Si powder addition on the phase composition，microstructure evolution，mechanical properties and thermal shock resistance of the low·-carbon MgO·-C matrix specimens were studied．The results show that after 1 2000C heating treatment，the Mg—A1 alloy has been oxidized and turned into MgAl204 through reaction between A1203 and MgO，it is also found that MgAl204 whiskers with a diameter in the range of 400—500nto and aspect ratio in the range of 30-40 were formed，and a Ni nanoparticle is located on the top of the Mghl204 whisker．After 1 4000C heating treatment，some new phases of A1N and SiC whiskers were formed while metallic Si was totally disappeared．At the same time，the quantity of MgAl204 formation WaS increaSed significantly；however,there were no significant change both on the diameter and the aspect ratio of MgAl204 whiskers．When the amount of Ni(N03)2’6H20 addition iS OVer 0．4wt．％．the thermal shock resistance and fracture toughness of specimens are improved sig