《模拟239Pu放射性废物的钆锆烧绿石固化及热学性能研究》 (1)》-毕业设计论文（公开)》-毕业设计论文（公开).docxVIP

PAGE I 西南科技大学本科生毕业论文 西南科技大学本科生毕业论文 PAGE III 模拟239Pu放射性废物的钆锆烧绿石 固化及热学性能研究 摘要：本研究利用Ce4+作为Pu4+的模拟替代物质，利用高温固相反应法开展固化体的制备，在对所制备固化体的物相及微观形貌等进行表征的基础上，对固化体的热稳定性（室温下热导率、比热、热扩散系数）进行研究。结果显示当固化体对Ce4+的固溶量超过10mol%时，在XRD图谱上，烧绿石的超晶格峰消失，固化体由烧绿石相转化为萤石相，在固溶量为10mol%时，通过SEM图片可以看出样品微观形貌不规则，呈板块状。本研究采用Hot Disk导热系数测定仪测量固化体的热导率、比热和热扩散系数,实验发现其热导率、比热和热扩散系数都随Ce4+的固溶量增加而增加。其研究成果将为今后锕系或次锕系核素人造岩石固化提供较为真实的科学数据。 关键词：239Pu；放射性废物；钆锆烧绿石；固化；热学性能  Reasearch of immobilizing simulated plutonium and thermal properties for Gd2Zr2O7 pyrochlore Abstract: The research used Ce4+ as the alternative material of 239Pu, and manufactured the solidified body by high temperature solid phase method, based on the phase and microstructure of the cured body prepared were characterized, this research studies on the thermal stability of the cured body (thermal conductivity, specific heat and thermal diffusivity at room temperature). The results showed that the superlattice peaks of Pyrochlore disappear , when the solution of Ce4+ in cured body is more than 10mol%, and the cured body changed from pyrochlore phase into fluorite phase.When the solution of Ce4+ is 10mol%，the morphology of the sample can be seen irregular and plate-like from the SEM images.This research uses Thermal conductivity detector with the Hot Disk method to measure the pyrochlore’s thermal conductivity, specific heat and thermal diffusivity, from this article it can be seen that the pyrochlore’s thermal conductivity, specific heat and thermal diffusivity is inscreased with the inscreasing of the solution of Ce4+. The research results will actinide or minor actinide synroc provide more real scientific data in the future. Key words: 239Pu, radioactive waste, gadolinium zirconate pyrochlore, solidification, thermal properties  目 录 TOC \o 1-3 \h \z \u HYPERLINK \l _Toc390004209 1 绪论 PAGEREF _Toc390004209 \h 1 HYPERLINK \l _Toc390004210 1.1 选题背景 PAGEREF _Toc390004210 \h 1 HYPERLINK \l _Toc39000