fefe3o4纳米粒子感器的制备及其在检测pb2和cu2中的应用.docx

优秀毕业论文 精品参考文献资料 Thesis tittle：The preparation of sensor based on Fe／Fe304 nanoparticles and its application in the detection of Pb2+and Cu2+ Thesis type：Applied basic research Professional discipline：Inorganic chemistry Graduate applicant：Yah Yang Adviser：Shiping Yang Abstract Magnetic nanoparticles(MNPs)are important nanomaterials with multiple fundamental properties，including superparamagnetism，high magnet蕊ion，high coercivity，and a macroscopic quantum tunneling effect and Can be easily modified by other molecules due to the functionalized groups Oil their surface，SO they have been widely used in food safety，environmental protection，and many other fields． MNPs-based magnetic sensors have many advantages over other sensors，for example， a significant improvement of sensitivity can be obtained by this method，different samples can be detected on the nuclear magnetic resonance instrument simultaneously， it dosen’t require expensive sophisticated instrumentation and complicated sample preparation processes and SO on，they have been developed to detect metal ions，small molecules，molecular interactions，proteins，bacteria，viruses and nucleic acids． The experiments are divided into two parts，and we separately studied some applications of 3-(3，4一dihydroxyphenyl)propionic acid modified Fe／Fe304 nanoparticles(DHCA-Fe／Fe304 NPs)and azide dopamine and mPEG-COOH modified Fe／Fe304 nanoparticles(N3一Fe／Fe304 NPs)in magnetic detection of Pb2+and Cu2+．The first part is the synthesis and application in detection of Pb2+of DHCA-Fe／Fe304 NPs．Firstly，synthesis Fe／Fe304 NPs through the high-temperature pyrolysis method，then DHCA was modified on the surface of nanoparticles by the ligand exchange method to obtain the water-soluble DHCA—Fe／Fe304 NPs．Because of the selective coordination interaction between DHCA and Pb2+．pb2+can induce the assembly of DHCA—Fe／Fe304 NPs accompanied by the decrease then increase in transverse relaxation time(72)of surrounding water protons．With the co