fe0tio2耦合微生物产电系统污染制研究.docx

优秀毕业论文 精品参考文献资料 The The Study of Pollution Control by Feo／Ti02 Catalytic Cathode Coupled in Microbial Fuel Cell System Abstract In this study，a novel water treatment system coupling(photo一)electrochemical catalysis rPEC or EC)in microbial fuel cell(MFC)was set-up using stainless steel(SS)cathode coated with Feo／Ti02．Feo／TiO：is prepared by a chemical reduction—deposition method and is coated onto SS wire mesh f500 mesh)using sol technique．We examined and compared the destruction of methylene blue(MB，20 mg／L)and tetracycline(1 00 mg／L)in different systems， photocatalysis(PC)，photoeIectrocatalysis(PEC)and our novel system，called～伍C-PEC／EC system。The results are as follows： f 1)The SS wire mesh coated l wt％Feo／Ti02 performed the best among the series of the prepared catalysts series(0．1％Feo／Ti02，0．5％Feo／Ti02，l％Feo／％02，3％Feo／Ti02，5％ Feo／Ti021．In photocatalysis system，it could remove 70．52％of the MB after 6 hours；in photoelectrocatalysis system．it could remove 78．62％ofthe MB after 6 hours． f2)l MFC—PEC／EC system(the noveI system with SS wire mesh coated l wt％ Feo／Ti02)，after 120 minutes，our novel system performed best when the microbial anode dosage was 54 g．removing 93．57％of MB．And the removal rate of MB(initial concentration was 20 mg／L、was better in the whole reaction process than when the M[B initiaI concentration was 40 mg／L．And when the DH value was 5．26 the system performed best，removing 94．84％ of MB，When the MFC．PEC system used 1 wt％Feo／Ti02 aS photocathode，the system performed best．The ESR study demonstrated that·0H was formed in the system both with visible light iIlumination and without light illumination． f31 The VOItage generated by the novel system was decreased at first，then increased and remained stable at last．When the cathode of MFC．PEC had l wt％Fe。／Ti02 as catalyst，the cell voltage was about 0．098 V，the power density was about l 3．72 mW／m2．The EEO relectrical energy consumpt ion per order of conversion)of MFC—PEC system was about 0。675 kWh／(m 3‘ord