cumnoxvmnox微纳米结构的制备及催化co氧化性能研究.docx

优秀毕业论文 精品参考文献资料 ABSTRACTThe ABSTRACT The catalytic oxidation of CO has been identified important reaction because of its wide applications in indoor air quality,gas sensors，C02 lasers，and automobile exhaust treatment．Although many studies have been devoted to the catalytic oxidation of CO using noble-metal catalysts such Au／Ti02，Au]Zr02 and Pt／Sn02，it is still greatly desked to explore the of less-expensive metal oxide catalysts with high activity and stability．This dissertation focuses the syntheses，characterizations and catalytic performances of micro／nanostruetured CuMnO。and VMnOx for CO oxidation，and is composed ofthree parts： In the first part，a series of CuMnOx catalysts were synthesized by pot pyrolysis method using mixed oxalate the precursor and their catalytic performances wfffe investigated for CO oxidation．The catalysts were characterized by X-ray diffaaction(XI①)，N2 physical adsorption(BED，scanning electron microscopy(SEM)，X-ray photoelectron spectroscopy(xPs)，and temperature-programmed reduction (TPR)．The effects of aging time and calcination temperature the structure and catalytic activity of CuMn204 catalyst also discussed in this study．The results suggested that the CuMnOx catalyst synthesized by pot pyrolysis method obtain single spinel CuMn204 phaSe with larger specific surface area and pore volume,which Can increase the amount of Cu-O-Mn interface required for CO oxidation reaction,therefore，a higher catalytic activity be obtained．Although bigrt calcination temperature could improve the crystallinity of C曲204，the specific surface area and pore volume well 器the exposed Cu-O-Mn interface of the catalyst decreaSed remarkably,which resulted in low CO conversion． In the second part，OMS-2 supports weie prepared by three different method and the supported copper oxide catalysts(CuO／OMS-2)were prepared by an incipient wetness impregnation method．The catalysts were characterized by X—ray diffraction(XRD)，N2 physical adsorption(BET)，transmission ele