基于电化学原理对有机氯农药毒死蜱的痕量检测.docVIP

PAGE 学校代码：11059 学号：0903021016 Hefei University BACHELOR DISSERTATION 论文题目 基于电化学原理对有机氯农药毒死蜱的痕量检测 学位类别 工学学士 学科专业 化学工程与工艺 完成时间 2013 06 01 基于电化学原理对有机氯农药毒死蜱残留痕量检测 中 文 摘 要 本文研究了电化学方法对有机氯农药毒死蜱的痕量检测，该方法相对于普通技术检测具有反应时间短、灵敏度高、条件要求不高等优点。本文基于毒死蜱分子的识别与探测的研究目标，采用双电位阶跃法，在Fe电极上沉积纳米Pd，制备Pd/Fe双金属电极，并详细地讨论了在制备电化学传感器中所要考虑的PH、富集时间，选择性等影响因素。实验表明，该电极对毒死蜱的氧化-还原有较强的电催化作用。在1×10-4~1×10-8mol/L的范围内，毒死蜱的还原峰有较好的线性增长关系，检测限为1×10-9mol/L。应用此电极制成的传感器痕量检测毒死蜱，具有响应快速、灵敏度高及选择性好等特点，且具有良好的再生性能。 关键词：Pd/Fe双金属体系；电沉积；毒死蜱；电化学行为 ；电极 electrochemical sensors preparation and trace immunoassay imidacloprid Abstract In this paper, a new method of detection of trace organochlorine pesticide named chlorpyrifos electrochemical method, which overcomes long reaction time, low sensitivity, inadequate conditions require higher in the detectionby ordinary skill. Based on the molecular identification of chlorpyrifos and detection of the target,in the use of electrochemical method, nano-palladium was　electrodeposited at Fe to preparing Pd/Fe electrode and discussed in detail in the preparation of the electrochemical sensor to be considered such as the pH, accumulation time, selectivity factors. Experiments show that the electrode has a strong electric catalysis to chlorpyrifos’s oxidation - reduction. In the 1 × 10-4 ~ 1 × 10-8mol / L range, the reduction peak of atrazine has a good linear relationship between growth, detection limit is 1 × 10-9mol / L. Application of this electrode is made of chlorpyrifos trace detection sensor with fast response, high sensitivity and good selectivity, and has good regeneration properties. Keywords: Pd/ Fe bimetallic system; electrodeposition; chlorpyrifos; electrochemical behavior ； electrode pole 目录 第一章 绪论 HYPERLINK \l _Toc16355 PAGEREF _Toc16355 1TOC \o 1-3 \h \u HYPERLINK \l _Toc4102 1.1 引 言 PAGEREF _Toc4102 3 HYPERLINK \l _Toc5678 1.1.1 电化学工作站基本原理及应用 PAGEREF _Toc5678 4 HYPERLINK \l _Toc22434 1.1.2 工作电极的选择 PAGEREF _Toc22434 5 HYPERLINK \l _Toc18992 1.