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In this work, we prepared a novel adsorbent by attaching TRG on silica-supported 3-aminopropyltriethoxysilane (SiO2-APTES)surface, and used for extraction of Cr (VI) in environmental water samples. The selectivity of the adsorbent toward the Cr (VI) species was improved by formation of a Cr (VI)-diphenylcarbazide complex prior to the adsorption. Complex formation between Cr(VI) and DPC is an interesting reaction for spectrophotometric determination of Cr(VI). This reaction has high selectivity for Cr (VI) versus Cr (III). The adsorbent has surface characteristics of graphene and graphene oxide such as large contact surface area and high amounts of polar groups on the surface. These properties results in high water-dispersibility of the adsorbent and provide a rapid adsorption process. The detection of the extracted Cr (VI) was performed with UV–vis spectrophotometry. The violet Cr (VI)-DPC complex exhibits a maximum absorption at 543 nm. Experimental Preparation of the adsorbent At first, silica-supported 3-aminopropyltriethoxysilane (SiO2-APTES) was prepared based on the literature. A portion of GO(0.4g) was added to 40 mL of distilled water and then, sonicated for 30min. Next, SiO2-APTES (20g) was placed in a beaker and the solution containing GO was added to it gradually (SiO2-APTES should not be dried in this step). Then, the mixture was heated up to 15?C for 20min. The precedure At first, pH of 25mL of the sample solution containing Cr (VI)(10ng mL-1) was adjusted at 1.7 by adding 0.5mL H2SO4(0.5 molL-1). Then, 150μL of DPC solution (10-2 mol L-1 in MeOH) was added to it to form the Cr (VI)-DPC complex. After 5 min, 0.5mL of SDS (1% w/v) was added to the sample solution.After that, 20 mg of the adsorbent was transferred to the sample solution and the mixture was sonicated for 1min. Subsequently,the solution containing the adsorbent was stirred for 3min. Next,the adsorbent was detached from the solution by centrifugation at 5500rpm for 3min, and then the su
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