甲基二氯硅烷甲醇醇解产物含量的红外与核磁共振分析.PDFVIP

21 6 JOURNAL O FNATIONAL UNIVERSITY O FDEFENSE TECHNOLOGY Vol. 21 No. 6 1999 (410073) MeSiHCl Me (OMe) SiH MeSi (OMe) 2 2 3 , : - , , Si H , , , , , , , 51 TQ 1 The Analysis of IR and H-NMR for the Concentration of the Alcoholysis Products of MeSiHCl2 Hu BiruSong YongcaiFeng Cunxiang (Department of Materials EngineeringApplied Chemistry, NUDT, changsha , 410073) Abstract In this paper , the alcoholysis products synthesized by MeSiHCl2 and MeOH in xylene are examined by 1 IR and H-NMR. The results indicated that theconcentration of each composition can becalculated using theSi-H bond and phenyl group absorption peak as spectrum-band of quantitative analysis through the calibration curveand thescaling method in the IR analytical means , and also it can beestablished using thenormalization method through theanalysis of 1 - . the different chemical shift parton H and aseries of quantitative analyticcalculations in H NMR Both methods are sim- ple and rapid. The results of the two methods arecompared. 1 Key words MeSiHCl , MeSi (OMe) , IR photometric method of multicomponents , quantitative analysis of H- 2 3 NMR. (Me( OMe)2SiH) , [1] , , [2] , , MeSiHCl2 , ,