金银和铜氰化溶解速率及硫离子对其影响的比较-中国有色金属学报.PDF

第 17 卷第 1 期 中国有色金属学报 2007 年 1 月 Vol.17 No.1 The Chinese Journal of Nonferrous Metals Jan. 2007 文章编号：1004-0609(2007)01-0172-07 金、银和铜氰化溶解速率及硫离子对其影响的比较 王 宇，陈 景，韦群燕，谢琦莹 (云南大学 化学系，昆明 650091) 摘 要：用旋转圆盘法在相同的实验条件下，对金、银、铜的氰化溶解速率进行比较研究。当氰化钠浓度为 5.00 g/L、圆盘转速为 600 r/min、温度为 30 ℃时，获得表观速率常数的顺序为：Au ＜Ag ＜Cu 。在氰化钠溶液中加入 微量硫化钠后，硫离子抑制氰化反应的影响程度则为：Au ＞Ag ＞Cu 。分析讨论了电化学反应机理，提出了相应 的观点并对实验结果进行了解释。 关键词：金；银；铜；氰化溶解；硫离子 中图分类号：0643.12 文献标识码：A Comparison of cyanidation rates of gold, silver and copper and influences of sulfion on them WANG Yu, CHEN Jing, WEI Qun-yan, XIE Qi-ying (Department of Chemistry, Yunnan University, Kunming 650091, China) Abstract: The cyanidation rates of gold, silver and copper were compared with each other under the same reaction conditions by kinetic rotating disk method, and the influences of sulfion on them were discussed. The results show that when the three metals react at ρ(NaCN) of 5.00 g/L, 600 r/min and 30 ℃ , the obtained apparent rate constants for cyanide dissolution of three metals accord with the order of Au＜Ag ＜Cu. However, when sodium sulfide is added into the cyanide solutions in advance, the decrease ratios of cyanide dissolution rates of the three metals accord with the order of Au ＞Ag ＞Cu. The reaction thermodynamics and mechanism based on the electrochemical theory were discussed, and some new explanations for experimental phenomena were proposed. Key words: gold; silver; copper; cyanidation; sulfion 19 世纪末，用氰化钠溶液从金矿石中提取金的方 曾出现过氧论、氢论、过氧化氢论、氰论、腐蚀论和