芳氨基螺芴类蓝色发光材料合成及荧光性能的研究Synthesisand.PDF

2011 年第 31 卷 有 机 化 学 Vol. 31, 2011 第 12 期, 2095～2101 Chinese Journal of Organic Chemistry No. 12, 2095～2101 ·研究论文· 芳氨基螺芴类蓝色发光材料合成及荧光性能的研究 李穿江 游红军 张智勇* 戴志群 关金涛 未本美 (武汉工业学院化学与环境工程学院 武汉 430023) 摘要 设计合成了一种新型二苯胺螺芴化合物 2,7-双二苯胺-螺环[芴-7,9-苯并芴](DDSF), 通过了 1HNMR, MS, IR 图谱 测试和元素分析, 每步反应产率均在 70% 以上; 利用紫外可见吸收光谱、荧光光谱研究了其发光性能. 结果表明, 在固 体状态下, 其荧光发射峰红移 40 nm 左右. 然而溶液荧光强度及荧光量子产率都随着溶剂极性的变化有着明显差异; 通过循环伏安法测得其氧化峰电位为 0.77 V, 计算出 DDSF 的 HOMO 能级为－5.10 eV, LUMO 能级为－2.95 eV. 关键词 芳胺螺芴; 合成; 光电性质; 蓝光材料 Synthesis and Optoelectronic Properties of an Arylamine-Endcapped Spirofluorene for Blue Light Emission Li, Chuanjiang You, Hongjun Zhang, Zhiyong* Dai, Zhiqun Guan, Jintao Wei, Benmei (Department of Chemical and Environmental Engineering, Wuhan Polytechnic University, Wuhan 430023) Abstract 2,7-Bis(diphenylamine)-spiro[fiuorene-7,9-benzofluorene] (DDSF) was successfully designed 1 and synthesized. Its structure was determined by H NMR, MS, IR and elemental analysis. The yield of each step was over 70%. Optoelectronic properties were investigated by UV-Vis absorption spectra and fluores- cence emission spectra. The results suggest that the maximum peak was red-shifted about 40 nm in solid state. However, the fluorescence emission spectra in solution and photoluminescence quantum yield were performed obviously difference along with the polarity of solvent. By cyclic voltammeter measurement and the gap calculated, the HOMO and LUMO energies of DDSF