超支化聚酯对聚乙二醇非等温结晶行为的影响-物理化学学报.PDF

物理化学学报(Wuli Huaxue Xuebao) 528 Acta Phys. -Chim. Sin . 2012, 28 (3), 528-535 March [Article] doi: 10.3866/PKU.WHXB201112202 超支化聚酯对聚乙二醇非等温结晶行为的影响 刘晶如* 徐 洁 董鸿超 俞 强 (常州大学材料科学与工程学院, 江苏常州213164) 摘要: 利用差示扫描量热法(DSC)、偏光显微镜(POM) 以及傅里叶变换红外(FTIR)光谱研究了一种超支化聚 酯(HBP)对聚乙二醇(PEG)非等温结晶行为的影响, 用Ozawa 法、Jeziorny 法和莫志深法对非等温结晶动力学 进行了分析. 结果表明: PEG 和HBP/PEG 的非等温结晶过程可用Ozawa 和莫志深动力学方程描述, 与 Jeziorny 动力学方程不符; 超支化聚酯的加入改变了PEG 的结晶成核和生长机理, 对PEG 的结晶有一定的延 缓作用. 超支化聚酯中的羰基与PEG 的端羟基形成的氢键以及超支化聚酯自身较大的分子体积和高度支化的 结构所导致的位阻效应是超支化聚酯延缓PEG 结晶的主要原因. 关键词: 聚乙二醇; 非等温结晶; 超支化聚酯; 差示扫描量热法 中图分类号: O643 Effect of Hyperbranched Polyester on the Non-Isothermal Crystallization Behavior of Polyethylene Glycol LIU Jing-Ru* XU Jie DONG Hong-Chao YU Qiang (School of Materials Science and Engineering, Changzhou University, Changzhou 213164, Jiangsu Province, P. R. China) Abstract: The effect of hyperbranched polyester (HBP) on the non-isothermal crystallization behavior of polyethylene glycol (PEG) was studied by differential scanning calorimetry (DSC), polarizing microscopy (POM), and Fourier transform infrared (FTIR) spectroscopy. The non-isothermal crystallization data for PEG and HBP/PEG were analyzed by the Ozawa, Jeziorny, and Mo Zhi-Shen methods. The results indicate that the non-isothermal crystallization processes of PEG and HBP/PEG may be described using the kinetic equations of Ozawa and Mo, but do not agree with the Jeziorny equation. The addition of HBP affected the crystallization process and crystal form of pure PEG, and slowed the rate of cr