化学活化和化学物理联合活化制备石油焦基活性炭.PDF

41 1 () Vol.41 No.1 2010 2 Journal of Central South University (Science and Technology) Feb. 2010 − ( 410083) − 2 C C N BET A B 2 2 CA 3 2 BET 61.28%0.35 g/cm 2 760 m /g CB 24.1%2.3 nm 1 A/g CA 137.8 F/gCB 20 A/g 1 A/g 4.7% − TQ424.1 A 1672−7207(2010)01−0050−05 Petroleum coke based activated carbon prepared from chemical activation and chemical-physical activation SUN Xiao-feng,WANG Xin-yu, LAI Yan-qing, ZHANG Zhi-an, XIA Yang (School of Metallurgical Science and Engineering, Central South University, Changsha 410083, China) Abstract: Taking petroleum cokes as raw material, activated carbons CA and CB were prepared by chemical activation and chemical-physical activation. The BET specific surface area and the pore structure of activated carbons were analyzed by N2 adsorption method. Electrochemical properties of both samples, such as constant-current charge-discharge measurement, cyclic voltammogram, and electrochemical impedance spectroscopy were investigated in non-aqueous electrolytes. It can be found that CA shows higher yield, tap density and BET specific surface area, which are 61.28%, 3 2 0.35 g/cm and 2 760 m /g, respectively. However, CB has higher mesopore ratio of 24.1% and pore diameter of 2.3 nm. At the current density of 1 A/g, CA attains the highest specific capacitance of 137.8 F/g. CB shows good power discharge behavior with the capacitance loss of 4.7% at the current density of 20 A/g than that at 1 A/g. Key words: petroleum coke; chemical activation; chemical-physical activation; activated carbon; supercapacitor