反应精馏设计和控制.pptVIP

反应精馏设计和控制 目录 文献阅读总结 1.Ung S, Doherty M F. Calculation of residue curve maps for mixtures with multiple equilibrium chemical reactions[J]. Industrial engineering chemistry research, 1995, 34(10): 3195-3202. 2.Ung S, Doherty M F. Vapor-liquid phase equilibrium in systems with multiple chemical reactions[J]. Chemical Engineering Science, 1995, 50(1): 23-48. 3.Qi Z, Kolah A, Sundmacher K. Residue curve maps for reactive distillation systems with liquid-phase splitting[J]. Chemical Engineering Science, 2002, 57(1): 163-178. 4.Sanchez-Daza O, Vidriales Escobar G, Morales Zárate E, et al. Reactive residue curve maps: A new study case[J]. Chemical Engineering Journal, 2006, 117(2): 123-129. 5.Thery R, Meyer X M, Joulia X, et al. Preliminary design of reactive distillation columns[J]. Chemical Engineering Research and Design, 2005, 83(4): 379-400. 文献阅读总结 1.Gao X, Li X, Zhang R, et al. Pressure Drop Models of Seepage Catalytic Packing Internal for Catalytic Distillation Column[J]. Industrial Engineering Chemistry Research, 2012, 51(21): 7447-7452. 2.Thiel C, Sundmacher K, Hoffmann U. Residue curve maps for heterogeneously catalysed reactive distillation of fuel ethers MTBE and TAME[J]. Chemical Engineering Science, 1997, 52(6): 993-1005. 3.Jiménez L, Wanhschafft O M, Julka V. Analysis of residue curve maps of reactive and extractive distillation units[J]. Computers Chemical Engineering, 2001, 25(4): 635-642. 4.Daza O S, Pérez‐Cisneros E S, Bek‐Pedersen E, et al. Graphical and stage‐to‐stage methods for reactive distillation column design[J]. AIChE journal, 2003, 49(11): 2822-2841. 课题想法 师兄文章思路：平衡控制的化学反应和气液相平衡级模型的研究简化情况，在反应段中化学反应平衡和气液相平衡同时达到。由此，反应段的状态可由气液相平衡曲面（泡点面）和反应平衡曲面共同描述。 缺陷：1.运用泡点面近似得到气液相平衡曲面而非通过严谨的热 力学计算得到。 2.所得到曲线仅能描述反应精馏内反应段的情况。 3.仅能描述A+B生成C的反应 改进：1.运用反应精馏剩余曲线描述反应段的实际组成情况，一条线代替原本的两条线。运用剩余曲线或者相平衡面描述非反应段的实际组成情况。完整的描述了全塔的组成。 2.引用元素为基准