添加剂对无烟煤炭阳极CO2反应性的影响-中国科技论文在线.PDF

中国科技论文在线 添加剂对无烟煤炭阳极CO2 反应性的影响# 孙智，任耀剑* （中国矿业大学材料学院,徐州 221116 ） 5 摘要：以优质低灰分无烟煤替代一部分石油焦作为原料制备炭阳极。研究了无烟煤炭阳极的 氧化度、脱落度、残极率和总的消耗速率四种指标，采用等温热重法测试不同添加剂 （Al 、 AlF3 、Al2O3 、CaF2、NaF 、MgO ）对无烟煤炭阳极的 CO2 反应活性的影响。研究结果表 明：在炭阳极中加入部分无烟煤不会对其 CO2 反应性带来不利影响；添加剂的种类对无烟 10 煤炭阳极的 CO2 有较大影响，其中含铝的添加剂能显著的降低炭阳极的 CO2 反应性。而 CaF2、NaF 则会增加无烟煤炭阳极的反应活性。 关键词：添加剂；无烟煤；炭阳极；CO2 反应性；电解铝 中图分类号：TF 15 Effect of Additives to CO2 Reactivity of Anthracite Carbon Anode SUN Zhi, REN Yaojian (School of Materials Science Engineering, China University of Mining Technology, Xuzhou 221116) 20 Abstract: Carbon anode was prepared with high quality and low ash anthracite substitution petroleum coke which was used as raw material. Four indicators such as the oxidation, the loss, the residual polar consumption rate and the total rate were studied in this paper, and isothermal gravimetric analysis was used to test various additives (Al, AlF3, Al2O3, CaF2, NaF, MgO) on anthracite carbon anode CO2 reactivity. The results show that the added anthracite has no adverse 25 effect on the CO2 reactivity of carbon anode. Types of additives have a greater impact on CO2 of anthracite carbon anode. Aluminum-containing additives can significantly reduce CO2 reactivity of carbon anodes. On contrary, CaF2, NaF would increase the reactivity of the anthracite carbon anode. Key words: additives; anthracite; carbon anode; CO2 reactivity; electroytic aluminium 30 0 引言 铝电解生产中，按式2Al O +3C=3CO +4Al ，阳极气体为100%的CO ，每生产1吨铝需消 2 3 2 2 耗炭