沥青基纳米炭纤维的制备与电化学性能研究.PDF

沥青基纳米炭纤维的制备与电化学性能研究 1 1 1 1 2,3 种传宾 , 刘丹丹 , 王静 , 时志强 *, 王成扬 1.天津工业大学 材料科学与工程学院 改性与功能纤维天津市重点实验室，天津300387 ； 2. 天津大学化工学院 绿色合成与转化教育部重点实验室，天津 300072 ； 3.天津化学化工协同创新中心，天津300072 摘要:采用静电纺织的方法制备沥青基纳米纤维并对其电化学性能进行研究。为了提高沥青 的可纺性，向沥青的四氢呋喃溶液中加入少量的PAN 溶液，调节纺丝原液浓度可控制沥青 基纳米纤维平均直径在250nm 左右。预氧化后，采用不同的温度对纤维进行碳化。通过SEM、 TEM 测试考察碳化前后的纤维直径的变化，并通过恒流充放电、循环伏安、交流阻抗等电 化学性能测试，确定碳化的最佳温度。实验结果表明：700℃碳化的沥青基纤维作为负极材 料组装的锂离子电池首次放电比容量达553 mAh/g ，远高于普通的负极材料，显示了高容量 负极材料的应用潜力。 关键词：静电纺丝 纳米纤维 沥青纤维 锂离子电池负极材料 中图分类号： TM912.9 文献标识码：A 文章编号： Preparation of pitch-based nanofiber and electrochemical properties 1 1 1 1 2,3 Chong Chuanbin , Liu Dandan , Wang Jing , Shi Zhiqiang *, Wang Chengyang 1.School of Materials Science and Engineering, Tianjin Key Laboratory of Fiber Modification and Functional Fiber, Tianjin Polytechnic University, Tianjin 300387, China 2 Key Laboratory for Green Chemical Technology of Ministry of Education, School of Chemical Engineering and Technology, Tianjin University, Tianjin 300072, P. R. China 3 Synergetic Innovation Center of Chemical Science and Engineering(Tianjin), Tianjin 300072, P. R. China Abstract Carbon fibers have many characteristics such as high thermal conductivity and high specific surface area, thus it is thought to be one of the ideal cathode materials for lithium ion batteries. At present, the main industrial carbon fibers are polypropylene nitrile carbon fibers. The industrial development of pitch-based carbon fiber was restricted by the complex modification of raw materials although pitch is rich source and has high carbonization rate. In this work, pitch-based nanofibers were prepared by electrospining and their electrochemical properties we