图78彩印疏水改性核壳结构颗粒对Pickering乳液的稳定作用.DOC

[在此处键入] 收稿日期：2018-00-00；定用日期：2018-00-00；DOI:10.13550/j.jxhg.201803190185 基金项目: 国家自然科学基金(217061478) 作者简介: 姜秋艳( 1994－) ，女，硕士研究生。联系人:李秋红( 1979－)，女，电话:0533-2782232，E－mail: qhli@ 功能材料 功能材料 （图7、8彩印）疏水改性核壳结构颗粒对Pickering乳液的稳定作用 201803190185 姜秋艳，李自闯，李秋红*，李爱香，丛日敏，司维蒙 （山东理工大学 材料科学与工程学院，山东 淄博 255000） 摘要：为了探究固体颗粒对乳液的稳定作用,采用双亲染料分子罗丹明B对核壳结构的Fe3O4@SiO2纳米颗粒进行疏水改性，并将改性后的纳米颗粒作为稳定剂制备Pickering乳液。通过Zeta电位、FTIR、XRD、SEM、接触角测量、光学显微镜、电导率仪对Fe3O4@SiO2纳米颗粒以及Pickering乳液的结构、形貌和性能进行表征与分析，结果表明：制备的纳米颗粒粒径小，约为150 nm，为单分散球形核壳结构；罗丹明B成功修饰到Fe3O4@SiO2纳米颗粒表面，改性后颗粒接触角由30°增加至120°；随乳化剂颗粒质量浓度的增加，制备的乳液液滴的粒径减小。另外，所得Pickering乳液具有良好的磁场响应性，可通过外加磁场实现对乳液稳定性的可逆调控，且此过程可重复3次以上。 关键词：罗丹明-B；疏水改性；Pickering乳液；磁场调控 中图分类号：O647 文献标志码：A 文章编号： Hydrophobic Modification of Core-shell Nanoparticles and Its Stabilizing Effect on Pickering Emulsions JIANG Qiu-yan, LI Zi-chuang, LI Qiu-hong*, LI Ai-xiang, CONG Ri-min, Si Wei-meng (School of Materials Science and Engineering, Shandong University of Technology, Zibo 255049, Shandong, China) Abstract: In order to explore the stabilizing effect of solid particles on the emulsions, core-shell Fe3O4@SiO2 nanoparticles were hydrophobically modified by Rhodamine B and then the resulting modified nanoparticles were used as stabilizer to prepare Pickering emulsions. The structure, morphology and properties of modified Fe3O4@SiO2 nanoparticles and Pickering emulsions were characterized and investigated by Zeta potential, FTIR, XRD, SEM, contact angle measurement, optical microscope and conductivity measurement. The results showed that mono-dispersed, spherical and core/shell structure nanoparticles with particle diameter 150 nm were synthesized successfully. Rhodamine B was successfully introduced onto the surface of Fe3O4@SiO2 nanoparticles. After Fe3O4@SiO2 nanoparticles was modified, its contact angle increased from 30° to 120°. The particle size of the emulsion droplets decreased with the increase of emulsifier mass concentration. Moreover, the resulting Pickering em