反相微乳液法制备纳米PMMA-SiO2复合微粒.PDF

第 47 卷 第 4 期 天津大学学报 (自然科学与工程技术版) Vol.47 No.4 2014 年 4 月 Journal of Tianjin University (Science and Technology) Apr. 2014 DOI:10.11784/tdxbz201205058 反相微乳液法制备纳米 PMMA-SiO2 复合微粒 许湧深，邱守季，杨 磊，葛 悦 (天津大学化工学院，天津 300072) 摘 要 ：以甲苯为连续相、水为分散相、十二烷基苯磺酸为乳化剂兼作催化剂、正戊醇为助乳化剂，制备反相微乳 液．然后引入正硅酸乙酯 (TEOS) ，在水核中形成二氧化硅纳米粒子．接着加入通过溶液聚合制备的甲基丙烯酸甲 酯 (MMA)和γ- 甲基丙烯酰氧基丙基三甲氧基硅烷 (KH570)共聚物的甲苯溶液，实现共聚物对纳米二氧化硅的包 覆．通过 TEM、FTIR 、TG 等测试，证实得到了共聚物包覆二氧化硅的核壳结构纳米粒，平均粒径约为 36,nm．当 共聚物中 KH570 质量分数为 5%时，获得最高的包覆率，聚合物占复合粒子质量的 47%． 关键词 ：反相微乳液；二氧化硅；包覆；纳米复合 中图分类号：O635 文献标志码 ：A 文章编号 ：0493-2137 (2014)04-0321-05 Preparation of PMMA-Silica Nanocomposite Particles by Inverse Microemulsion Method Xu Yongshen ，Qiu Shouji ，Yang Lei ，Ge Yue (School of Chemical Engineering and Technology ，Tianjin University ，Tianjin 300072 ，China) Inverse microemulsions were prepared with toluene as continuous phase, water as dispersed phase, dode- Abstract ： cylbenzene sulfonic acid (DBSA) as emulsifier and catalyst, and n-pentanol as co-emulsifier. Then tetraethylorthosili- cates (TEOS) were introduced into the inverse microemulsion to hydrolyze and condense, forming nanosilica particles in the water pools. Subsequently the solutions of copolymer of methyl methacrylate (MMA) and γ- methacryloxypropyltrimethoxy silane (KH570) in toluene were added to the inverse microemulsion. Thus the nanosili- cas were encapsulated by copolymer via the co-condensation reaction of silanols between the copolymers and silica. It was evidenced by TEM, FTIR,