含铜-氮配键腰果酚醛缩聚物的特性及表征-林产化学与工业.PDF

23 3 Vol. 23 No. 3 2003 9 Chemistry and Industry of Forest Products Sept. 2003 - 陈 玉, 林金火* ( 福建师范大学高分子研究所, 福建福州350007) CHEN Y : , , , CuCl , - IR( DMTA) TG 2 , , , , - : ; ; ; - :TQ63; O636 :A :0253- 2417(2003) 03- 0061- 04 CHARACTERI ATION OF CARDANOL-ALDEHYDE CONDENSATION POLYMER CONTAINING COPPER-NIT ROGEN COORDINATED BOND CHEN Yu, LIN Jin-huo ( Inst it ut e of Polymer Scie nce, Fuj ian N or mal Un iv er si ty , Fuz hou 350007, Chi na) Abstract: Cardano-l aldehyde condensation resin(CF) is susceptible to corrosion by alkali because of its slight acidity of phenolic hydroxyls. CF was modified by aniline, followed by reaction with CuCl .The final product of the co-con- 2 densation polymer containing copper-nitrogen coordinated bond(CFNCu) has been synthesized and characterized by IR, dynamic mechanical thermogram analysis ( DMTA) and other measures. Results show that copper-nitrogen coordinated bond increases the cross-linking of coating film, leading to the remarkable improvements of physico- mechanical properties,thermo-stability and resistance against chemical media, especially alkali. Key words:cashew nut shell liquid; cardano-l aldehyde condensation polymer; aniline; Cu-N coordinated bond [ 1] , ( CF) , , [2] , OH, CF , , CF , [3~ 5] , NH , , 2 :2002- 11- 14 : ( ; ( E0110022) : ( 1979- ) , , , , : * 62