煤的高效催化燃烧及固硫一体化技术.pptVIP

* The integrated technology of catalysis and sulfur retention during coal combustion is one of the important means of coal efficient and clean utilization, and it is one of the national “85” “95” Gongguan projects. By spraying additive into boiler during coal combustion, the activity of carbon combustion can be improved while the sulfur in coal can be retented in the ashes. Comparing with other technology of coal utilization, this method has many advantages such as simple process, low investments and operation costs, tiny reformation to boiler, etc. The integrated additives composed of crude minerals and industrial dregs developed by DICP are superior to the conventional calcium-based sulfur sorbents. The commercial test on a 130 ton/hr pulverized coal boiler at AnGang No.1 power plant shows that 60% of SO2 is removed at 1.75 Ca/S molar ratio (from 430 ppm to 170 ppm), and no distinct influences of the heat efficiency of the boiler are observed. The technology can be widely used in the industrial and power plant boilers, especially in the boilers of lower operating temperature, stove, fluid-bed boiler and pulverized coal boiler. On Mar. 18, 2000, the technology had been authenticated by CAS and the S T Committee of Liaoning Province. Now the technology is being applied on a 220 ton/hr pulverized coal boiler of Guangzhou Petroleum and Chemical Plant. 煤 的 高 效 催 化 燃 烧 及 固 硫 一 体 化 技 术 INTEGRATED TECHNOLOGY OF CATALYSIS AND SULFUR RETENTION DURING COAL COMBUSTION 能源环境工程组技术简介 11 的高效催化燃烧及固硫一体化技术是煤炭高效清洁利用的重要 手段之一，是国家“八五”及“九五”重点科技攻关项目，其 基础理论研究已被列入国家“973”计划。 在煤中加入适量添加剂，可以降低碳燃烧反应活化能，从而降低反应温度，提高反应速度，缩短燃烧时间，使燃烧放热更加集中；同时添加剂又能与燃烧过程中产生的SO2作用生成硫酸盐而将硫留在灰渣中，达到催化燃烧和固硫的双重目的。此项技术投资少，运行费用低，工艺简单，操作方便，同时不须对现有炉具进行改造，是适合于现阶段中国国情的一项脱硫技术，特别适用于运行温度较低的锅炉、民用炉灶、流化床锅炉以及煤粉锅炉，尤其对老牌排污企业的技术改造具有吸引力。 我所与鞍钢大连石灰石矿联合研制开发的以多种纯天然矿物和工业废料为成分的DCL型燃煤固硫剂其各项技术经济指标均优于传统单一的钙基固硫剂。在鞍钢第一发电厂130吨/小时煤粉炉上进行的工业试运行结果表明，在Ca/S摩尔比为1.75时，除尘器前烟道气出口SO2浓度降低60%，固硫剂的使用对锅炉工况及热