双酚A型二氰酸酯及其环氧改性体系的反应性研究.PDF

A 27 A Study on Cur ing React ion of Bis phenol A Dicyanat e Est er and It s Epoxy M odif ied Syst ems 1 2 2 , , 1 , 710048; 2 , 710072) 1 2 2 REN P eng- gang , L IA N G Guo- zheng , ZH A N G Zeng- ping 1 Inst it ut e of Pr int ing and Packaging Engineering, Xi. an Universit y of T echnolo gy, Xi. an 7 10048, China; 2 Depar tm ent o f A pplied Chemist ry , Scho ol of Science, Nor thw est er n Po lyt echnical Universit y, Xi. an 710072, China) : A BADCy ) , DSC, FT IR BA DCy , , BAD Cy 180 e ) , 200 e ) , , , : ; ; ; : T Q3231 5 : A : 100 1- 4 38 1 2008) 04- 0027- 06 Abstract: T he react ion mechanism and product st ruct ur e o f bisphenol A dicyanat e est er BA DCy) r es- in and its epo xy E5 1 and E20) m odif ied syst em s w ere inv estig at ed by DSC and FT IR . T he r esults show ed that t he po lycy clo tr im eriz e react io n t ook place in BA DCy. While t he m ain r eact ion in epox ies modif ied syst em at low t em perat ure 180 e ) w ere: Cy clo tr im er iz at ion of cyanat es, poly et her ficat ion of epox y g roups and cyclot rimerizat io n of cyclic dimm ers and t he fo rmat io n of ox az oline r ing. A t high temperature 200 e ) , t he fo rmat ion of ox az olidinone ring w ere dominant . T he content s of cyclot r-i m er iz at ion , po lyet herf icat io n, o xazo line ring and o xazo