基于btea的可uv固化水性聚氨酯合成与性能研究-材料加工工程专业论文.docxVIP

AbstractABSTPACT Abstract ABSTPACT Due to their linear structure and hydrophilic ionic bonds，the conventional waterborne polyurethane(wPu)exhibit poor water resistance，inferior solvent resistance and unfavorable mechanical properties，which restrict their further application．UV technology has been developed fast in recent years for its“5E’’ characteristics(Efficient，Energy-saving，Environmental-friendly，Economical and Enabling)．The UV curd resins exhibit high hardness，high solvent and water resistance and good mechanical properties due to its high crosslink density．UV curable polyurethane dispersion(uv—PUD)combines the advantages of both WPU and UV curing systems，such as environmental friendly，fast curable speed，energy saving，excellent performance of films，etc．The conventional UV—PUD is prepared by using a single hydroxyl acrylate to terminate the polyurethane prepolymer．Therefore， the obtained resins couldn’t possess both high C=C content and high molecular weight at the same time which result in defects of the cured films．In order to solve thjS problem，acrylic diols were synthesized to incorporate into PU chains．But the synthetic process of acrylic diol is somewhat complicated and the reaction condition is very harsh，which have greatly limited its further application． In this dissertation，a novel diol，2-(3-(((2，2一bis(hydroxymethyl)butoxy) carbonylamino)methyl)一3，5，5·trimethylcyclohexylcarbamoyloxy)ethyl acrylate (BTEA)，Was synthesized by a facile reaction．The new diol Was incorporated into the polyurethane side chains in different ratios to obtain UV二PUD．nle properties of emulsion and the corresponding UV cured films were investigated，respectively． 1．A novel acrylic diol(BTEA)Was synthesized by a facile urethane reaction． 111e structure of the diol was confirmed by Fourier Transform Infrared spectroscopy 口TIR)and Hydrogen Nuclear Magnetic Resonance(1H-NMR)．The effects of catalyst，reaction temperature，reaction time and the reactant molar ratio were investigated． 2．A