第三期-顾振华.pptVIP

谈谈实验室安全和实验的个人体会 导师：麻生明 研究员 汇报人：顾振华 主要内容 实验室安全 个人的实验 科学的信誉问题 Giving Proper Credit 控温仪 毛细管 温度计、温度计套管 核磁管 高温高压反应 多借鉴别人的经验 LiAlH4：Workup best conducted by “1,2,3-method” for 1.0 g LiAlH4 used, added 1 mL H2O (slowly) then 2 mL of 10% aqueous NaOH, then 3 mL of H2O 无故乱翻书 8 : 2规则 基于呋喃酮骨架的周环反应研究 The mechanism study The plausible pathway Researcher Withdraws JACS Papers Dalibor Sames Professor of chemistry, Columbia University Bengü Sezen Sames was not able to speak with CEN because the matter is under investigation by Columbia. Sezen could not be reached by CEN press time. 小结 Conditions: (a) C2H5Br, Mg, THF, then acetylene; (b) CD3COCD3, 34%; (c) NaH, Et2O, then ClCO2Me, 71%; (d) n-BuLi, Et2O, -78 oC; then H2O, -78 oC, 38%; (d) 2-allyl-4-phenylbuta-2,3-dienoic acid, Pd(OAc)2/TFP, K2CO3, DMSO, 54%, 95%D. Giving Proper Credit Chemical Engineering News March 12, 2007 Volume 85, Number 12 pp. 35-38 Researchers who have been directly affected by Córdovas actions ……. say Córdova steals research ideas at conference and then presents the ideas as his own by publishing the results of hasty and often poorly executed parallel experiments. Córdova Donna G. Blackmond, a professor of chemistry at Imperial College, says Córdova stole her scientific ideas at a lecture, published them, and continues to present her development of a new model explaining nonlinear effects in organocatalysis as if it were his own. Its fair to say that Córdova has a pretty bad reputation in the community, and it seems he is resubmitting things he has heard about in lectures, says Benjamin List. List says that after he spoke a conference in Italy, Córdova submitted similar work that was published in Tetrahedron Letters. He says he blames himself for talking about the work, but he adds, People know whats going on. Sweden, Stockholm University In 2001, Córdova submitted a research paper to the Journal of the American Ch