梳型紫外光快速固化聚氨酯的制备及涂层性能朱亚丽董运生陈丽杰.DOCVIP

ADDIN CNKISM.UserStyle梳型紫外光快速固化聚氨酯的制备及涂层性能 朱亚丽，董运生，陈丽杰，姚有为，洪阳阳，唐国翌* （清华大学 深圳研究生院 能源与环境学部，广东 深圳518055） 摘要：以1,3-丙二醇、甲基丙烯酸缩水甘油酯为主要原料，无水四氯化锡为催化剂，三氟乙酸为助催化剂，合成了一种具有光化学活性的聚醚（PGMA）。此聚醚以碳氧键为主链，以甲基丙烯酸酯基为梳型侧链，端基为羟基。将上述具有光化学活性的聚醚（PMGA）与异佛尔酮二异氰酸酯（IPDI）反应，制得具有光化学活性的聚氨酯〔Poly(PGMA-IPDI)〕。在上述聚氨酯中加入活性稀释剂和光引发剂，制备出一种能够快速光固化的树脂，固化时间可以达到1s，柔韧性达到0.5mm、附着力为最高级0级，同时固化涂层在盐溶液、水溶液、碱溶液中浸泡无脱落，在酸性水溶液中脱落时间也达到36h请多用数据说话，中英文一并修改已改正，中英文相应 请多用数据说话，中英文一并修改 已改正，中英文相应数据已补充。 关键词：紫外光固化；聚醚；阳离子聚合；聚氨酯树脂 中图分类号：TQ314 文献标识码：A Synthesis of the Comb-like Rapid UV-cured Polyurethane and Its Film Properties ZHU Yali, DONG Yunsheng, CHENG Lijie, YAO Youwei, HONG Yangyang, TANG Guoyi*姓字母全部大写已改正， 姓字母全部大写 已改正，姓的字母已大写。 (Division of Environment Energy, Graduate School at Shenzhen, Tsinghua University, Shenzhen 518055,Guangdong,China) Abstract: The study developed an efficient method for the synthesis of a novel photosensitive polyether via cationic ring-opening polymerization of glycidyl methacrylate using 1,3-propanediol as a precursor, and tin tetrachloride and trifluoroacetic acid as catalysts. The hydroxyl-terminated polyether (PGMA) contains comb-like methacrylate groups as its side chains. Then, new polyurethane acrylate (poly(PGMA-IPDI)) was prepared by the reaction of PGMA and isophorone diisocyanate (IPDI). Meanwhile, the targeted structure of PGMA and poly(PGMA-IPDI) was confirmed by FT-IR and 1H NMR. The UV-curable coatings were prepared by the incorporation of poly(PGMA-IPDI) oligomers into formulations together with reactive diluents and photoinitiators, which exhibited excellent properties such as curing speed, flexibility and chemical-solvent resistance. Remarkably, the UV-curable coatings could cured by exposure to ultraviolet radiation in just one second. Meanwhile, the UV-curable coatings not only have no peel off from sheet iron within 48h in solvent resistant experiments, but also remained unchange for 36h in acidic aqueous solution. Key words: UV-cured; polyether; cationic polymerization; po