喷墨打印用包裹型硫硒化镉颜料的制备-材料科学与工程专业论文.pdf.docxVIP

作为水相，采用微乳．水热法成功制备出了被硅酸锆包裹的硫硒化镉红颜料。 作为水相，采用微乳．水热法成功制备出了被硅酸锆包裹的硫硒化镉红颜料。 微乳液中小液滴的粒径约为25 nm，水热时间为18小时，水热温度为200℃， 硒粉含量为0．08 g，以正丁醇为助表面活性剂，包裹层ZrSi04与被包裹层 CdSl．xSex的比值等于2：1时，制备的红度值最高的硫硒化镉颜料的粒径约为 10 nm，包裹率为15．9％；在所制备的颜料的应用性研究中，添加30 mL曲 拉通时，所制备的模拟墨水的沉降时间相对较长，为26小时，适当改善制 备条件有可能得到性能更好的陶瓷墨水。 关键词：喷墨打印，大红颜料，硫硒化镉，包裹 Ⅱ 万方数据 PREnU王ATION PREnU王ATION oF CADMnJM SULFo．SELENIDE 矾CLUSIoN PIGMENTS FoR INK．皿T PRIN田叭G ABSTRACT The ceramic ink is jetted on the various dielectric surface through the jet nozzle of the head of printer．Small drops of ink made from ceramic pigments come out of nozzle with tens of microns diameter and deposit on the carrier at the speed of thousands of drops per second based on ink-jet printing technology． Compared with other printing ways，ink-jet printing has many incomparable advantages．For example，products uS如g ink-jet printing technology has the extremely high accuracy and resolution,strong stereo sense，excellent simulation effect,and well production repeatability．It is convenient to realize no-contact with any design and color ofpersonalized printing． Ink-jet printing technology is a low noise，non-contact and high speed digital printing method which can realize text and image printing．The key to the ink-jet printing techno logy is the preparation o f ceramic pigments for ceramic ink．As a ceramic pigment,it must frst be not able to change its color in high temperature．That is to say,ceramic pigments for证k-jet printing must have stable chemical performance under hj曲temperature．Second，it must be able to withstand the erosion of the glaze and have stable chemical performance and color under hi．曲temperature．That is the b iggest difference舶m the general inorganic pigment on the properties．In addition,ceramic pigment must have smaller particle size without grinding． (1)ZrSiOdCdSl．xSex red pigment has been synthesized successfully via sol-gel-hydrothermal method，uS访g ZrOCl2‘8H20，Na2Si03‘9H20，Na2S‘9H20， CdS04。8／3H20，Se powder as the sources．The high temperature of 1