电喷法制备表面改性钛氧颗粒及电流变性能-材料表面工程专业论文.pdf.docxVIP

电喷法制备表面改性钛氧颗粒及电流变性能Electrorheological 电喷法制备表面改性钛氧颗粒及电流变性能 Electrorheological Properties of Surfactant Modified Titanium Oxide Particles Prepared by Electrostatic Spraying Method Abstract Electrorheological(ER)fluids is a sort of suspension system which consist of micron and nanon polarizable particles dispersed in dielectric oil．ER fluids have broad application prospects in electrical control components with such features as reversible regulatioIl，rapid response，energy conversion．The property of ER fluids is subject to the morphology and component of dispersible particles．At present，the preparation method of ER particles is liquid-phase method that has some defects of technology resulting in uncontrollable shape and size of particles，low purity，which severely put a brake on the development of ER fluids．To cope with the problem，we first adopted a more suitable method named electrostatic spraying (ES)to prepare ER particles whose chemical composition is titanium oxide(TiO。)modified by polyvinylpyrrolidone(PVP)and stearic acid(SA)．Meanwhile，we studied on the process of ES and selected hydrolysis-precipitation(HP)method as the representative of tradition method．By comparing the ER effect of ES—TiO。／PVP／SA particles and HP—TiOx／PVP／SA particles．we proved the ER performance of TiOx／PVP／SA particles prepared by ES method is more excellent． The main research contents and conclusions are as follows： (1)In the experimental process，the main technological parameters of ES method are PVP and Tetra-n-butyl Titanate(TBT)solution content，voltage，receive distance．We used controlling variables method to study the relationship between these parameters and particles’ morphology．Through the comparison and analysis，The optimal process parameters is ascertained 2Ls：mass fraction of PVP is O．5％，mass fraction of TBT is 1 5％，voltage is 20kV and receive distance is 5cm． (2)To contrastively study on ES—TiO√PVP／SA and ES—TiOx／PVP particles，we used scanning electron microscope(SEM)，X-ray(XRD)a