离子液体与5-羟甲基糠醛及其衍生物相互作用的红外和核磁光谱研究-物理化学专业论文.docxVIP

优秀毕业论文 精品参考文献资料 ABSTRACT5-Hydroxymethylfurfural(5-HMF)derived ABSTRACT 5-Hydroxymethylfurfural(5-HMF)derived from biomass has been considered green platform compound，which has wide range of applications in manufacturing fine chemicals and biofuels．Ionic liquids(ILs)have shown superior performance in the conversation of biomass to 5-HMF as reaction medium and／or catalyst。Nevertheless，the separation of 5-HMF from ILs is very difficult and becomes technical bottleneck for ILs application in the preparation of 5-HMF．To resolve this problem，the understanding about the interactions between ILs and 5-HMF is essential．Therefore，as part of the project supposed by the National Natural Science Foundation of China(No．2 1 573060)，the effects of anionic structure snd ring type of the cation of the ILs the hydrogen bonding interactions between ionic liquids and 5-HMF its derivatives have been investigated in the present work．The interaction modes and the interaction sites between ILs and 5-HMF its derivatives have been analyzed．The main contents follows． 1．The hydrogen bonding interactions between ILs and 5-HMF were determined function of mole fraction of 5-HMF in 5-HMF．ionic liquids binary mixtures(including【Bmim][CH3COO]， [Bmim][CF3coo]，[Bmim][C2H5COOl，[Bmim][HS04]，[Bmim][N03]，[Bmim][CH30S03]，[Bmiml[OTq， [Bmim][N(CN)2】，[Bmim][BF4])by ATR-FTIR and 1H NMR at 293K．The influence of anion species of ionic liquids the hydrogen bonding interactions between ILs and 5-HMF has been investigated．It was found that the formation capability of hydrogen bonding of anion with 5-HMF was decreased in the sequence：[CH3coo]+，【C2H5COOl一[HS04]’[CF3COO]‘lN03]‘【N(CN)2】。[CH30803]。【OTf]。 【BF4】_． 2．ATR．FTIR and 1H NMR spectra have been used to investigate the hydrogen bonding interactions in the binary mixtures of[BuPy][N03]／5一HMF,[PYl4][N03]／5-HMF,[PPl4][N03]／5·HMF and [(Bu)BNH][N03]／5一HMF at 293K．The influence of cationic structures of the ionic liquids the hydrogen bonding interactions between ILs