锂离子电池材料tio2基复合纳米线陈列的制备及电化学性能研究-材料学专业论文.docxVIP

优秀毕业论文 精品参考文献资料 研究生优秀毕业论文 AbstractAt Abstract At prescnt，carbon materials have been widely used in commercial lithium ion battery· Among these carbon materials，鲫hene has low operating voltage and exhibits good electrochcrnical performance．But using grahene imposes safety issues because of the formation of lithium dendrites．Therefore，OVer the past decades，a worldwide effort has been made to search for alternative anode materials．Due to its high Li intercalating potential which can avoid the formation of lithium denote，titanium dioxide(Ti02)is one of the most promising new anode materials．Thanks to its controllable shape，large space distance， 口olycrstal structure，abundant resources and environmentally friendly，Ti02 has been widely used in lithium ion battery．However，owe to its low specific capacity and poor electronic conductivity。the electrochemical performance of Ti02 anode is still not satisfactory·In order to improve the specific capacity and conductivity of Ti02，we prepared Ti02。based nanowire an．avs and investigated their effects on the electrochemical performances．We hope to provide a new path for the research of lithium ion battery anode to promote its commerel甜 applications． Fristlv，we prepared Ti02 nanowire arrays by a simple hydrothermal reaction·X。ray diffraction and Raman results showed that we got different phases of Ti02(Anatase and Ti02(B))．Then we studied its electrochemical performances as the anode for lithium ion battery without polymer binders and conductive agents．Compared with the standard Degussa P25 Ti02 nanoparticles，the Ti02 nanowire arrays exhibited larger reversible capactty， improved cycling stability and rate capability，which attributed to their nanowlre array structure． In order to improve the capacity，we successfully prepared Ti02@Fe203 composite which Was a core-branch hybrid architecture．It could not only provide large surface active sites for lithium ion insertion／extraction，but also enable fast charge transport owing to the red