聚(n-异丙基丙烯酰胺)(pnipaam)银纳米粒子复合物的制备及其动态sers研究-高分子化学与物理专业论文.docxVIP

优秀毕业论文 精品参考文献资料 Abstract Abstract Shanghai Normal University Master of Philosophy The composite nanofiber mats also showed good reproducibility and stability．What’S more，the strong interaction between PNIPAAm and urea was applied in the direct SERS detection of adenosine in urea solution without urea interferance．Together with the advantages of ease of large-scale fabrication，inexpensive，stable and‘laser sensitivity”，AgNPs／PNIPAAm composite nanofiber mats might find application in sensitive multicomponent biosensing． By using RAFT polymerization and the reduction of NaBH4，PNIPAAm—SH was obtained，and AgNPs@PNIPAAm were fabricated by mixing AgNPs and PNIPAAm—SH to form the chemical bond between Ag and S atoms． AgNPs@PNIPAAm served as SERS substrate can be used for the detection of PAHs， which have a good SERS sensitivity．This can be contributed to the hydrophobic property of PNIPAAm with the evaporation of solvent．And the AgNPs@PNIPAAm have a salt tolerance．These founding provide new insight into an attractive of AgNPs and polymer composite nanomaterials that can find application in the SERS detection of organic pollutant in river and sea． Key Words：Surface-Enhanced Raman Scattering；Poly(N—isopropylacrylamide) (PNIPAAm)；Silver nanopartides；extra-stimulus responsibility；Dynamic SERS V 万方数据 上海师范大学硕士学位论文 上海师范大学硕士学位论文 目录 目录 第一章绪论 ．．1 1．1表面增强拉曼散射光谱的研究进展 ．2 1．1．1表面增强拉曼散射的原理机制 2 1．1．2表面增强拉曼散射的应用 4 1．2 SERS活性基底的构建 5 1．2．1金属粗糙电极 5 1．2．2贵金属纳米粒子 5 1．2．3贵金属纳米薄膜和岛膜 6 1．2．3花型、枝状及核壳结构的金属纳米复合材料 6 1．2．4贵金属纳米阵列 7 1．3贵金属纳米粒子与智能聚合物复合物的研究进展 ．7 1．3．1无规则填充型智能NMNPs复合物 9 1．3．2规则填充型智能NMNPs复合物 ．．11 1．3．3表面覆盖型智能NMNPs复合物 一12 1．3．4核壳结构型智能NMNPs复合物 ．．13 1．4本文研究内容及其研究意义 14 第二章聚(N．异丙基丙烯酰胺)／银纳米粒子复合物的制备及其动态SERS检测 ．．17 2．1引言 1 7 2．2实验部分 1 8 2．2．1材料与试剂 ．1 8 2．2．2仪器 ．．1 8 2．2．3 PNIPAAm膜的制备 18 2．2．4银溶胶(AgNPs)的制备 ．．19 2．2．5 PNIPAAm／AgNPs复合膜的制备 19 2．3结果与讨论 19 2．3．1 PNIPAAm／AgNPs复合膜的表征 19 2．3．2 PNIPAAm／AgNPs复合膜的温度响应性对SERS信号的影响 22 2．3．3 PN