甲基丙烯酸酯系二元共聚树脂的吸油性能Oil-南华大学学报.PDFVIP

24 2 () Vol. 24 No. 2 2010 6 Journal ofUn iversity of outh China( cience and Technology) Jun. 2010 : 1673- 0062( 2010) 02- 0084- 05 苯乙烯- 甲基丙烯酸酯系二元共聚树脂的吸油性能 吴红枚, 李 竞, 邱长平, 刘传湘, 刘芝芳 ( , 421001) : 采用悬浮聚合法, 以 BPO 为引发剂, DVB 为交联剂, HEC为分散剂, 甲苯为 孔剂, 合 了苯乙烯分别与甲基丙烯酸甲酯甲基丙烯酸 丁酯甲基丙烯酸十二酯 的二元共聚树脂. 研究了反应时间及温度引发剂交联剂分散剂原料配比烷基酯 的长度对树脂吸油性能的影响. 所制得的树脂对甲苯的吸油率分别可达 9g/g 12g/g14g /g, 对乙酸乙酯的吸油率分别可达 7. 8g/g8. 4g/g10. 5g /g. 在显微镜下对 树脂吸油前后的内部微观结构进行了观察对比. : 高吸油性树脂; 苯乙烯; 甲基丙烯酸酯; 吸油率; 显微镜照相 : O63 : A Oil- absorption Power of Series of Styrene- methacrylate Copolmers WU Hong-me,i LI Jing, QIU Chang-ping, LIU Ch an-xiang, LIU Zhi-fang ( chool of Chem istry and Chem icalEngineering, University of outh China, Hengyang, Hunan 421001, China) Abstract: eries of h igh oil absorbent copolymer resins w ere synthesized by suspension polymerization, in wh ich styrene w as used as the firstmonomer, m ethylm ethacrylate, butyl methacrylate and dodecylmethacrylate as the secondmonomer respectively. Polymerization reactions proceeded w ith dibenzoyl peroxide ( BPO ) as the initiator, divinyl benzene ( DVB) as the cross- link ing agent, hydroxyethyl cellu lose (HEC) as the d ispersing a- gen,t toluene as the pore form ing agent. W e focus on the effect of the tmi e, different tem- peratures, the amount of BPO, DVB andHEC, themolar ratio of raw material, differentmo- lecu lar chain length of the second monomers on the oil absorption pow er of the copolymer resins. It is shown that oil- absorption pow er of the resinesw ere up to 9g/g, 12g /g, 14g/ g, w h ile that of ethyl acetatew ere up to 7. 8g/g, 8. 4g/g, 10. 5g/g respectively. M