添加剂在半水硫酸钙表面的吸附特征研究-华东理工大学学报.PDFVIP

DOI: 10.14135/ki.1006-3080.20180312001 添加剂在半水硫酸钙表面的吸附特征研究 付文健，林美庆，何慧艳，陈杰， 程雲， 赵 敏* (华东理工大学化学与分子工程学院，上海，200237) 摘 要: 本文以有机羧酸为添加剂，研究聚丙烯酸（PAA ）、柠檬酸(CA)在半水硫酸钙（HCS ）表 面的吸附作用和吸附机理。采用总有机碳分析仪（TOC）分析添加剂在HCS 表面的吸附特征，透射 电镜-能量损失谱（TEM-EELS) 、X 射线电子能谱（XPS ）、激光显微拉曼光谱、傅里叶红外光谱（FTIR ） 等微观表征方法对吸附层结构进行分析，最后结合 HCS 晶体结构探讨添加剂的吸附机理。结果表明 有机羧酸在HCS 表面的吸附符合Langmuir 等温吸附理论，吸附动力学更符合二级反应。 关键词: 柠檬酸；聚丙烯酸；吸附；络合 中图法分类号：O742+.7 文献标志码：A Adsorption Characteristics of Additives on Hemihydrate Calcium Sulfate F U Wen-jian ，LIN Mei-qing，HE Hui-yan ，CHEN Jie，CHENG Yun， ZHAO Min * （College of Chemistry and Molecular Engineering, East China University of Science and Technology, 200237) Abstract: In this paper, the adsorption and adsorption mechanisms of polyacrylic acid (PAA) and citric acid (CA) on the surface of calcium sulfate hemihydrate (HCS) were studied using organic carboxylic acids as additives. The adsorption characteristics of additives on HCS surface were analyzed using TOC. TEM-EELS, X-ray electron spectroscopy (XPS), laser Raman spectroscopy, Fourier infrared FTIR and other microscopic characterization methods were used to analyze the adsorption layer structure. Finally, the adsorption mechanism of additives was explored in combination with the crystal structure of HCS. The results show that the adsorption of organic carboxylic acid on the surface of HCS conforms to the Langmuir isotherm adsorption theory, and the adsorption kinetics was more consistent with the secondary reaction. Organic carboxylic acid was synthesized through the carboxyl group on the molecular 2+ structure and Ca on the surface of gypsum, so as t