《纳米二硼化锆粉体的制备与表征论文》-毕业论文设计（可用）.docVIP

辽宁科技大学本科生毕业设计（论文） 第 PAGE 30页 纳米ZrB2粉体的制备 摘 要 二硼化锆陶瓷粉体是一种黑色粉末，其化学分子式为：ZrB2，分子重量112.84，密度4.52g/cm3，是六方晶系的准金属结构化合物，是一种高级工程材料，在各个领域有着广泛应用。高熔点(3040℃)、高硬度、高稳定性以及良好的导电性、导热性、抗氧化性和抗化学腐蚀性，使以二硼化锆为原料制成的复合陶瓷综合性能优异。另外，二硼化锆具有良好的中子控制能力，可用于核工业。其各种优良特性使其成为很有发展前景的高性能耐火材料。采用了透射电镜(TEM)实验测试技术对制备的纳米粉体进行表征。以氯氧化锆为锆源，以NH3?H20与ZrOCL2?8 H20生产沉淀剂，利用特殊液相沉淀法制备了纳米Zr(OH)2粉体。将沉淀至于NH4BO3溶液中，分别用烘干和共沸剔除水分，消除使硼酸吸附纳米Zr(OH)2上，通过在氢气环境下，煅烧Zr(OH)2和NH4BO3消除氮氢氧，从而制得纳米硼化锆。在上通过扫描电镜分析研究了锆源浓度、NH3?H20和H3BO3的用量、溶胶pH值、陈化时间等因素对硼化锆颗粒大小的影响。本文实验研究部分研究了用NH4?H20为沉淀剂法制得的纳米硼化锆粉体，颗粒粒径随硼酸溶液的浓度增大而减小。研究在不同温度下煅烧Zr(OH)2和NH4BO3的混合物，与NH4Cl一起作为沉淀剂法制得的纳米二硼化锆粉体，颗粒粒径随温度的浓度增大而减小。 关键字：纳米；二硼化锆；制备；表征 Preparation of nano-ZrB2 powder Abstract Diboride zirconium ceramic powder is a black powder, the chemical formulas for ZrB2, molecular weight 112.84, 4.52 g/cm3 density, is six FangJing department must metal structure compound, is a kind of advanced engineering materials, has a wide application in all fields. High melting point (3040 ℃), high hardness and high stability and good electrical conductivity and thermal conductivity, oxidation resistance and corroZrB2 resistance of chemical resistance, make with diboride zirconium as raw material made of composite ceramic comprehensive performance is excellent. In addition, diboride zirconium has good neutron control ability, can be used for the nuclear industry. The variety of fine properties that make it a very promising high performance refractory. This paper used the nano experimental center of our patent technology, special liquid preparation of nanometer particle ZrB2 precipitation. Using transmisZrBn electron microscopy (TEM) test technology on the preparation of nanometer powder characterized. To chlorine zirconia for zirconium source, NH3 ?H20 and ZrOCL2 ?8 H20 precipitation agent production, use special liquid preparation of nanometer Zr precipitation (OH) 2 powder. As for NH4BO3 solution will precipitation, respectively for drying and boiling wat