《玻璃微珠的改性论文》-毕业论文设计（可用）.docVIP

本科毕业设计（论文） 玻璃微珠的改性 学 院 专 业 年级班别 学 号 学生姓名 指导教师 年 月 空心 空心玻璃微珠的改性 摘要 空心玻璃微珠具有中空、质轻、密度小、粒径均匀等优点，通过对其进行表面改性，可以得到质轻、易回收的功能微珠。一般的玻璃微珠是绝缘体，若对其表面进行化学镀银，则使其具有良好的导电性能。 空心玻璃微珠这种超细粉体材料，其比表面积较大，在其表面进行化学镀银会容易降低镀液的稳定性，因此选择合适的化学镀工艺非常重要。本实验研究了玻璃微珠表面化学镀银不同的工艺参数，选择葡萄糖作为还原液，银氨溶液为主盐溶液，选择碱洗、粗化、敏化、活化的预处理步骤，然后对预处理后的玻璃微珠实施化学镀银。对预处理每个步骤都进行优化，并利用正交试验对镀银过程的条件进行最优化。通过万能电用表对其进行压实电阻检测，得出最优方案：预处理每个步骤进行的时间均为10min，粗化剂用10g/L亚硫酸铵水溶液，敏化剂SnCl2溶液定为20g/L，活化时AgNO3浓度为10g/L。镀银过程中条件确定为：温度常温（25℃），反应时间为1h，葡萄糖浓度为15g/L，PH值为12。最优方案得出的实验成品压实电阻检测为0.1Ω。结果显示：本实验正交优化的方法能够制得导电性能较好的镀银空心玻璃微珠。 关键词：玻璃微珠，改性，化学镀银，导电性能 Abstract As a kind of fine powder materials, cenosphere is endowed with many characteristics, such as hollow, light weight, small size and non-toxicity. Usually, glass beads is an insulator, if carried to its surface silver plating, it has a good electrical conductivity. cenospheres’ specific surface is high ,so the bath stabilization is reduced while doing electroless platinhe. So it is important to select feasible process of electroless nickel plating to control the bath stabilization, deposition speed at some extent and dispersing of cenospheres in the bath uniformly. This study based on many glass beads modified electroless plating methods. Pretreatment program for hollow glass beads are alkaline cleaning, coarsening, sensitization, activation. And silver plating with silver ammonia solution and glucose. Optimize the pretreatment by single factor experiment but the electroless plating by orthogonal test. And testing the compact resistance by the multimeter. The optimal technological conditions are obtained, each pretreatment program time is 10 min, coarsening using 10 g/L ammonium sulfite solution, SnCl2 solution at 20 g/L, concentration of AgNO3 at 10 g/L. In the process of silver plating conditions identified as, temperature under normal temperature (25℃) , reaction time of 1 h, concentrations of glucose at 15 g/