离子交换树脂静态吸附二甲胺的研究.PDF

中国环境科学 2010,30(9) ：1183~1188 China Environmental Science 离子交换树脂静态吸附二甲胺的研究 孟媛媛 1,胡勤海 1*,孙同喜 2,陆侨治 3,熊云龙 3 (1.浙江大学环境与资源学院,浙江 杭州 310029 ；2.浙江工业 大学生物与环境工程学院,浙江 杭州 310032 ；3.杭州金枫叶科技有限公司,浙江 杭州 310012) 摘要：通过静态吸附实验,研究了二甲胺在 ZGSPC106 型细颗粒树脂上的吸附行为,从热力学和动力学角度对吸附过程进行了分析,并用红 外光谱的方法探讨了树脂吸附二甲胺的机理.结果表明, Langmuir 等温方程能够很好的拟合吸附平衡数据,热力学参数表明该吸附可自发 进行,且为熵增加的吸热过程,293K 温度下树脂的静态饱和吸附容量为 138.89mg/g(干树脂);吸附动力学符合准二级动力学模型,颗粒扩散 是树脂吸附二甲胺速率的主要控制步骤. 关键词：二甲胺；离子交换树脂；吸附 中图分类号：X703 文献标识码：A 文章编号：1000-6923(2010)09-1183-06 1 1* 2 Static adsorption property of dimethylamine on ion exchange resin. MENG Yuan-yuan , HU Qin-hai , SUN Tong-xi , LU George3 3 , XIONG Yun-long (1. College of Environmental and Resources Science, Zhejiang University, Hangzhou 310029, China; 2. College of Biological and Environmental Engineering, Zhejiang University of Technology, Hangzhou 310032, China; 3. Golden Maple Leaf Corporation of Hangzhou, Hangzhou 310012, China). China Environmental Science, 2010,30(9)：1183~1188 Abstract ：The fine grained resin ZGSPC106 was used to adsorb dimethylamine (DMA) from aqueous solution in the present research. Batch experiments were performed to analyze the thermodynamics and kinetics of adsorption. Results showed the equilibrium adsorption data were conformed satisfactorily to the Langmuir equation. The evaluation based on Langmuir isotherm gave the maximal static saturated adsorption capacity of 138.89mg/g at 293K. Various thermodynamic parameters such as free energy (∆Go o o ), enthalpy (∆H ) and entropy (∆S ) showed that the adsorption was spontaneous, endothermic and feasible.